TY - JOUR
T1 - Novel group 14 elements-bridged self-assembled supramolecules from pyrimidine derivatives and palladium ions
AU - Miura, Yoshiyuki
AU - Nanjo, Masato
AU - Mochida, Kunio
AU - Iwamoto, Takeaki
AU - Kira, Mitsuo
PY - 2004/9
Y1 - 2004/9
N2 - A solvent-free complex of dimethyldi(5-pyrimidyl)silane with (ethylenediamine)palladium dinitrate in ratio of 1:3 afforded hitherto unknown three-dimensional, silicon-bridged, self-assembled, cage-like supramolecule via dative: bonding to the transition metal centers. The structure of the supramolecule was fully identified by spectroscopic methods and X-ray diffraction analysis. A germanium analogue was also prepared in the same way.
AB - A solvent-free complex of dimethyldi(5-pyrimidyl)silane with (ethylenediamine)palladium dinitrate in ratio of 1:3 afforded hitherto unknown three-dimensional, silicon-bridged, self-assembled, cage-like supramolecule via dative: bonding to the transition metal centers. The structure of the supramolecule was fully identified by spectroscopic methods and X-ray diffraction analysis. A germanium analogue was also prepared in the same way.
KW - Heavier carbon homologues
KW - Pyrimidine derivatives
KW - Supramolecule
KW - X-ray diffraction
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U2 - 10.1016/j.inoche.2004.07.004
DO - 10.1016/j.inoche.2004.07.004
M3 - Article
AN - SCOPUS:4544306608
SN - 1387-7003
VL - 7
SP - 1017
EP - 1018
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
IS - 9
ER -