TY - JOUR
T1 - Novel method for the fabrication of a charge-transfer complex crystal by photoirradiation
AU - Matsuda, Masaki
AU - Nishi, Miki
AU - Koga, Shoko
AU - Fujishima, Mika
AU - Hoshino, Norihisa
AU - Akutagawa, Tomoyuki
AU - Hasegawa, Hiroyuki
PY - 2014/9/1
Y1 - 2014/9/1
N2 - A novel method for the fabrication of a charge-transfer complex crystal was developed. Photoirradiation of a solution of TPP[Co(tbp)(CN)2] and TPP[Co(Pc)(CN)2] (tbp=tetrabenzoporphyrin, Pc=phthalocyanine, TPP=tetraphenylphosphonium) gave a molecular conducting crystal of a charge-transfer complex TPP[Co(tbp)(CN)2]2, which was produced by the process in which the photoexcited electron in tbp was transferred from the LUMO of tbp to that of Pc. Crystal growth: Photoirradiation of a solution of TPP[Co(tbp)(CN)2] and TPP[Co(Pc)(CN)2] (tbp=tetrabenzoporphyrin, Pc=phthalocyanine, TPP=tetraphenylphosphonium) gave a molecular conducting crystal of a charge-transfer complex TPP[Co(tbp)(CN) 2]2, which was produced by the process in which the photoexcited electron in tbp was transferred from the LUMO of tbp to that of Pc (see figure).
AB - A novel method for the fabrication of a charge-transfer complex crystal was developed. Photoirradiation of a solution of TPP[Co(tbp)(CN)2] and TPP[Co(Pc)(CN)2] (tbp=tetrabenzoporphyrin, Pc=phthalocyanine, TPP=tetraphenylphosphonium) gave a molecular conducting crystal of a charge-transfer complex TPP[Co(tbp)(CN)2]2, which was produced by the process in which the photoexcited electron in tbp was transferred from the LUMO of tbp to that of Pc. Crystal growth: Photoirradiation of a solution of TPP[Co(tbp)(CN)2] and TPP[Co(Pc)(CN)2] (tbp=tetrabenzoporphyrin, Pc=phthalocyanine, TPP=tetraphenylphosphonium) gave a molecular conducting crystal of a charge-transfer complex TPP[Co(tbp)(CN) 2]2, which was produced by the process in which the photoexcited electron in tbp was transferred from the LUMO of tbp to that of Pc (see figure).
KW - charge-transfer complexes
KW - crystal growth
KW - photocrystallization
KW - phthlaocyanines
KW - porphyrins
UR - http://www.scopus.com/inward/record.url?scp=84906951403&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84906951403&partnerID=8YFLogxK
U2 - 10.1002/chem.201402644
DO - 10.1002/chem.201402644
M3 - Article
AN - SCOPUS:84906951403
SN - 0947-6539
VL - 20
SP - 11318
EP - 11321
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 36
ER -