We performed in-situ inelastic light scattering measurement in KNbGeO 5 glass with a high nucleation ability during heating in order to elucidate nanocrystallization dynamics. The results of the in-situ measurement and TEM observation revealed that nanometric heterogeneous region (∼1-2 nm) consisting of the Nb-richer phase develops, i.e., K3Nb 7O19, at the temperature, in which glassy-supercooled- liquid (SCL) phase-transition occurs, i.e., precursive stage of nanocrystallization. This strongly suggests that evolution of the nanometric Nb-richer phase in the SCL phase corresponds to nucleation in the KNbGeO 5 glass.
|Journal||IOP Conference Series: Materials Science and Engineering|
|Issue number||SYMPOSIUM 8|
|Publication status||Published - 2011|
|Event||3rd International Congress on Ceramics, ICC3 - Osaka, Japan|
Duration: 2010 Nov 14 → 2010 Nov 18