On-line mass spectrometry for ethanol oxidation on well-defined Sn/Pt(hkl) electrode surfaces

H. Nakamura; T. Inoue; T. Matsuda; N. Todoroki; T. Wadayama

doi:10.1149/07514.1029ecst

On-line mass spectrometry for ethanol oxidation on well-defined Sn/Pt(hkl) electrode surfaces

H. Nakamura, T. Inoue, T. Matsuda, N. Todoroki, T. Wadayama

ENV - Frontier Science for Advanced Environment

Tohoku University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Onset potentials of ethanol oxidation reaction (EOR) and potential-dependent evolution of gaseous products from well-defined Sn/Pt(hkl) electrode surfaces were investigated. The electrode surfaces were prepared by vacuum deposition of Sn on a Pt(hkl) single-crystal substrate in ultra-high vacuum. The EOR onset potentials of anodic currents for Sn/Pt(hkl) shifted to lower potentials in comparison to unmodified Pt(hkl). Online electrochemical mass spectrometry (OLEMS) analysis of the gaseous products formed on the Sn/Pt(hkl) surfaces showed that acetaldehyde, rather than CO₂, was generated at lower applied voltages and that the product evolution was sensitive to the atomic arrangement of the surface Pt (Pt(hkl)). EOR anodic current measurements and OLEMS analysis showed that EOR onset potential is the lowest for Sn/Pt(110). The findings can be attributed to the effectiveness of Pt(110) steps in ethanol C-C bond cleavage and an ensemble effect of the Pt and Sn atoms against CO poisoning.

Original language	English
Title of host publication	Polymer Electrolyte Fuel Cells 16, PEFC 16
Editors	D. J. Jones, H. Uchida, H. A. Gasteiger, K. Swider-Lyons, F. N. Buchi, P. N. Pintauro, B. S. Pivovar, K. E. Ayers, K. A. Perry, P. Shirvanian, A. Z. Weber, V. K. Ramani, P. Strasser, R. A. Mantz, K. Shinohara, S. Mitsushima, C. Coutanceau, J. M. Fenton, T. J. Schmidt, T. F. Fuller, S. R. Narayanan, Y. T. Kim, L. Zhuang, S. G. Sun
Publisher	Electrochemical Society Inc.
Pages	1029-1033
Number of pages	5
Edition	14
ISBN (Electronic)	9781607687313, 9781607687672, 9781607687689, 9781607687696, 9781607687702, 9781607687719, 9781607687726, 9781607687733, 9781607687740, 9781607687757, 9781607687771, 9781607687788, 9781607687795, 9781607687801, 9781607687818, 9781607687825, 9781607687832, 9781607687849, 9781607687856, 9781607687863, 9781607687887, 9781607687894, 9781607687900, 9781607687917, 9781607687924, 9781607687931, 9781607687948, 9781607687955, 9781607687962, 9781607687979, 9781607687986, 9781607687993, 9781607688006, 9781607688013, 9781607688020, 9781607688037
DOIs	https://doi.org/10.1149/07514.1029ecst
Publication status	Published - 2016
Event	Symposium on Polymer Electrolyte Fuel Cells 16, PEFC 2016 - PRiME 2016/230th ECS Meeting - Honolulu, United States Duration: 2016 Oct 2 → 2016 Oct 7

Publication series

Name	ECS Transactions
Number	14
Volume	75
ISSN (Print)	1938-6737
ISSN (Electronic)	1938-5862

Conference

Conference	Symposium on Polymer Electrolyte Fuel Cells 16, PEFC 2016 - PRiME 2016/230th ECS Meeting
Country/Territory	United States
City	Honolulu
Period	16/10/2 → 16/10/7

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Nakamura, H., Inoue, T., Matsuda, T., Todoroki, N., & Wadayama, T. (2016). On-line mass spectrometry for ethanol oxidation on well-defined Sn/Pt(hkl) electrode surfaces. In D. J. Jones, H. Uchida, H. A. Gasteiger, K. Swider-Lyons, F. N. Buchi, P. N. Pintauro, B. S. Pivovar, K. E. Ayers, K. A. Perry, P. Shirvanian, A. Z. Weber, V. K. Ramani, P. Strasser, R. A. Mantz, K. Shinohara, S. Mitsushima, C. Coutanceau, J. M. Fenton, T. J. Schmidt, T. F. Fuller, S. R. Narayanan, Y. T. Kim, L. Zhuang, ... S. G. Sun (Eds.), Polymer Electrolyte Fuel Cells 16, PEFC 16 (14 ed., pp. 1029-1033). (ECS Transactions; Vol. 75, No. 14). Electrochemical Society Inc.. https://doi.org/10.1149/07514.1029ecst

Nakamura, H. ; Inoue, T. ; Matsuda, T. et al. / On-line mass spectrometry for ethanol oxidation on well-defined Sn/Pt(hkl) electrode surfaces. Polymer Electrolyte Fuel Cells 16, PEFC 16. editor / D. J. Jones ; H. Uchida ; H. A. Gasteiger ; K. Swider-Lyons ; F. N. Buchi ; P. N. Pintauro ; B. S. Pivovar ; K. E. Ayers ; K. A. Perry ; P. Shirvanian ; A. Z. Weber ; V. K. Ramani ; P. Strasser ; R. A. Mantz ; K. Shinohara ; S. Mitsushima ; C. Coutanceau ; J. M. Fenton ; T. J. Schmidt ; T. F. Fuller ; S. R. Narayanan ; Y. T. Kim ; L. Zhuang ; S. G. Sun. 14. ed. Electrochemical Society Inc., 2016. pp. 1029-1033 (ECS Transactions; 14).

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title = "On-line mass spectrometry for ethanol oxidation on well-defined Sn/Pt(hkl) electrode surfaces",

abstract = "Onset potentials of ethanol oxidation reaction (EOR) and potential-dependent evolution of gaseous products from well-defined Sn/Pt(hkl) electrode surfaces were investigated. The electrode surfaces were prepared by vacuum deposition of Sn on a Pt(hkl) single-crystal substrate in ultra-high vacuum. The EOR onset potentials of anodic currents for Sn/Pt(hkl) shifted to lower potentials in comparison to unmodified Pt(hkl). Online electrochemical mass spectrometry (OLEMS) analysis of the gaseous products formed on the Sn/Pt(hkl) surfaces showed that acetaldehyde, rather than CO2, was generated at lower applied voltages and that the product evolution was sensitive to the atomic arrangement of the surface Pt (Pt(hkl)). EOR anodic current measurements and OLEMS analysis showed that EOR onset potential is the lowest for Sn/Pt(110). The findings can be attributed to the effectiveness of Pt(110) steps in ethanol C-C bond cleavage and an ensemble effect of the Pt and Sn atoms against CO poisoning.",

author = "H. Nakamura and T. Inoue and T. Matsuda and N. Todoroki and T. Wadayama",

note = "Publisher Copyright: {\textcopyright} 2016 The Electrochemical Society.; Symposium on Polymer Electrolyte Fuel Cells 16, PEFC 2016 - PRiME 2016/230th ECS Meeting ; Conference date: 02-10-2016 Through 07-10-2016",

year = "2016",

doi = "10.1149/07514.1029ecst",

language = "English",

series = "ECS Transactions",

publisher = "Electrochemical Society Inc.",

number = "14",

pages = "1029--1033",

editor = "Jones, {D. J.} and H. Uchida and Gasteiger, {H. A.} and K. Swider-Lyons and Buchi, {F. N.} and Pintauro, {P. N.} and Pivovar, {B. S.} and Ayers, {K. E.} and Perry, {K. A.} and P. Shirvanian and Weber, {A. Z.} and Ramani, {V. K.} and P. Strasser and Mantz, {R. A.} and K. Shinohara and S. Mitsushima and C. Coutanceau and Fenton, {J. M.} and Schmidt, {T. J.} and Fuller, {T. F.} and Narayanan, {S. R.} and Kim, {Y. T.} and L. Zhuang and Sun, {S. G.}",

booktitle = "Polymer Electrolyte Fuel Cells 16, PEFC 16",

edition = "14",

}

Nakamura, H, Inoue, T, Matsuda, T, Todoroki, N & Wadayama, T 2016, On-line mass spectrometry for ethanol oxidation on well-defined Sn/Pt(hkl) electrode surfaces. in DJ Jones, H Uchida, HA Gasteiger, K Swider-Lyons, FN Buchi, PN Pintauro, BS Pivovar, KE Ayers, KA Perry, P Shirvanian, AZ Weber, VK Ramani, P Strasser, RA Mantz, K Shinohara, S Mitsushima, C Coutanceau, JM Fenton, TJ Schmidt, TF Fuller, SR Narayanan, YT Kim, L Zhuang & SG Sun (eds), Polymer Electrolyte Fuel Cells 16, PEFC 16. 14 edn, ECS Transactions, no. 14, vol. 75, Electrochemical Society Inc., pp. 1029-1033, Symposium on Polymer Electrolyte Fuel Cells 16, PEFC 2016 - PRiME 2016/230th ECS Meeting, Honolulu, United States, 16/10/2. https://doi.org/10.1149/07514.1029ecst

On-line mass spectrometry for ethanol oxidation on well-defined Sn/Pt(hkl) electrode surfaces. / Nakamura, H.; Inoue, T.; Matsuda, T. et al.
Polymer Electrolyte Fuel Cells 16, PEFC 16. ed. / D. J. Jones; H. Uchida; H. A. Gasteiger; K. Swider-Lyons; F. N. Buchi; P. N. Pintauro; B. S. Pivovar; K. E. Ayers; K. A. Perry; P. Shirvanian; A. Z. Weber; V. K. Ramani; P. Strasser; R. A. Mantz; K. Shinohara; S. Mitsushima; C. Coutanceau; J. M. Fenton; T. J. Schmidt; T. F. Fuller; S. R. Narayanan; Y. T. Kim; L. Zhuang; S. G. Sun. 14. ed. Electrochemical Society Inc., 2016. p. 1029-1033 (ECS Transactions; Vol. 75, No. 14).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - On-line mass spectrometry for ethanol oxidation on well-defined Sn/Pt(hkl) electrode surfaces

AU - Nakamura, H.

AU - Inoue, T.

AU - Matsuda, T.

AU - Todoroki, N.

AU - Wadayama, T.

PY - 2016

Y1 - 2016

N2 - Onset potentials of ethanol oxidation reaction (EOR) and potential-dependent evolution of gaseous products from well-defined Sn/Pt(hkl) electrode surfaces were investigated. The electrode surfaces were prepared by vacuum deposition of Sn on a Pt(hkl) single-crystal substrate in ultra-high vacuum. The EOR onset potentials of anodic currents for Sn/Pt(hkl) shifted to lower potentials in comparison to unmodified Pt(hkl). Online electrochemical mass spectrometry (OLEMS) analysis of the gaseous products formed on the Sn/Pt(hkl) surfaces showed that acetaldehyde, rather than CO2, was generated at lower applied voltages and that the product evolution was sensitive to the atomic arrangement of the surface Pt (Pt(hkl)). EOR anodic current measurements and OLEMS analysis showed that EOR onset potential is the lowest for Sn/Pt(110). The findings can be attributed to the effectiveness of Pt(110) steps in ethanol C-C bond cleavage and an ensemble effect of the Pt and Sn atoms against CO poisoning.

AB - Onset potentials of ethanol oxidation reaction (EOR) and potential-dependent evolution of gaseous products from well-defined Sn/Pt(hkl) electrode surfaces were investigated. The electrode surfaces were prepared by vacuum deposition of Sn on a Pt(hkl) single-crystal substrate in ultra-high vacuum. The EOR onset potentials of anodic currents for Sn/Pt(hkl) shifted to lower potentials in comparison to unmodified Pt(hkl). Online electrochemical mass spectrometry (OLEMS) analysis of the gaseous products formed on the Sn/Pt(hkl) surfaces showed that acetaldehyde, rather than CO2, was generated at lower applied voltages and that the product evolution was sensitive to the atomic arrangement of the surface Pt (Pt(hkl)). EOR anodic current measurements and OLEMS analysis showed that EOR onset potential is the lowest for Sn/Pt(110). The findings can be attributed to the effectiveness of Pt(110) steps in ethanol C-C bond cleavage and an ensemble effect of the Pt and Sn atoms against CO poisoning.

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DO - 10.1149/07514.1029ecst

M3 - Conference contribution

AN - SCOPUS:84991691542

T3 - ECS Transactions

SP - 1029

EP - 1033

BT - Polymer Electrolyte Fuel Cells 16, PEFC 16

A2 - Jones, D. J.

A2 - Uchida, H.

A2 - Gasteiger, H. A.

A2 - Swider-Lyons, K.

A2 - Buchi, F. N.

A2 - Pintauro, P. N.

A2 - Pivovar, B. S.

A2 - Ayers, K. E.

A2 - Perry, K. A.

A2 - Shirvanian, P.

A2 - Weber, A. Z.

A2 - Ramani, V. K.

A2 - Strasser, P.

A2 - Mantz, R. A.

A2 - Shinohara, K.

A2 - Mitsushima, S.

A2 - Coutanceau, C.

A2 - Fenton, J. M.

A2 - Schmidt, T. J.

A2 - Fuller, T. F.

A2 - Narayanan, S. R.

A2 - Kim, Y. T.

A2 - Zhuang, L.

A2 - Sun, S. G.

PB - Electrochemical Society Inc.

T2 - Symposium on Polymer Electrolyte Fuel Cells 16, PEFC 2016 - PRiME 2016/230th ECS Meeting

Y2 - 2 October 2016 through 7 October 2016

ER -

Nakamura H, Inoue T, Matsuda T, Todoroki N , Wadayama T. On-line mass spectrometry for ethanol oxidation on well-defined Sn/Pt(hkl) electrode surfaces. In Jones DJ, Uchida H, Gasteiger HA, Swider-Lyons K, Buchi FN, Pintauro PN, Pivovar BS, Ayers KE, Perry KA, Shirvanian P, Weber AZ, Ramani VK, Strasser P, Mantz RA, Shinohara K, Mitsushima S, Coutanceau C, Fenton JM, Schmidt TJ, Fuller TF, Narayanan SR, Kim YT, Zhuang L, Sun SG, editors, Polymer Electrolyte Fuel Cells 16, PEFC 16. 14 ed. Electrochemical Society Inc. 2016. p. 1029-1033. (ECS Transactions; 14). doi: 10.1149/07514.1029ecst

On-line mass spectrometry for ethanol oxidation on well-defined Sn/Pt(hkl) electrode surfaces

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