Zur kristallchemie des ersten blei-zink-silicium-telluroxids: PbZn4SiTeO10

B. Wedel; K. Sugiyama; K. Hiraga; K. Itagaki

doi:10.1515/znb-1999-0409

Zur kristallchemie des ersten blei-zink-silicium-telluroxids: PbZn₄SiTeO₁₀

Translated title of the contribution: On the crystal chemistry of the first lead zinc silicon tellurium oxyde PbZn₄SiTeO₁₀

B. Wedel, K. Sugiyama, K. Hiraga, K. Itagaki

Materials Development Division

Research output: Contribution to journal › Article › peer-review

Abstract

Single crystals of the new lead zinc silicon tellurium oxide PbZn₄SiTeO₁₀ have been prepared by solid state reaction in air. The compound is colourless and crystallizes in orthorhombic symmetry, space group D¹⁶_2h Pnma, with the cell parameters: a = 6.542 (5), b = 15.624(4), c = 8.280(4) Å, Z = 4. The structure has been determined from a single crystal X-ray study and refined to the conventional values R = 0.032 and wR(F²) = 0.050. Zn²⁺ and Si⁴⁺ show tetrahedral and Te⁶⁺ octahedral coordination by O^2-.Thecrystal structurels dominated by a ³_∞ [Zn₄O₁₀]^12- framework with isolated TeO₆⁶⁺ and SiO₄⁴⁺ polyhedra. Pb²⁺ ions are incorporated in the network. The centres of negative charge of the lone pairs of Pb²⁺ are estimated by calculations of the Coulomb term of the lattice energy.

Translated title of the contribution	On the crystal chemistry of the first lead zinc silicon tellurium oxyde PbZn₄SiTeO₁₀
Original language	German
Pages (from-to)	469-472
Number of pages	4
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	54
Issue number	4
DOIs	https://doi.org/10.1515/znb-1999-0409
Publication status	Published - 1999 Apr

Keywords

Crystal Structure
Lead
Silicon
Tellurium
Zinc

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1515/znb-1999-0409

Cite this

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title = "Zur kristallchemie des ersten blei-zink-silicium-telluroxids: PbZn4SiTeO10",

abstract = "Single crystals of the new lead zinc silicon tellurium oxide PbZn4SiTeO10 have been prepared by solid state reaction in air. The compound is colourless and crystallizes in orthorhombic symmetry, space group D162h Pnma, with the cell parameters: a = 6.542 (5), b = 15.624(4), c = 8.280(4) {\AA}, Z = 4. The structure has been determined from a single crystal X-ray study and refined to the conventional values R = 0.032 and wR(F2) = 0.050. Zn2+ and Si4+ show tetrahedral and Te6+ octahedral coordination by O2-.Thecrystal structurels dominated by a 3∞ [Zn4O10]12- framework with isolated TeO66+ and SiO44+ polyhedra. Pb2+ ions are incorporated in the network. The centres of negative charge of the lone pairs of Pb2+ are estimated by calculations of the Coulomb term of the lattice energy.",

keywords = "Crystal Structure, Lead, Silicon, Tellurium, Zinc",

author = "B. Wedel and K. Sugiyama and K. Hiraga and K. Itagaki",

year = "1999",

month = apr,

doi = "10.1515/znb-1999-0409",

language = "German",

volume = "54",

pages = "469--472",

journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

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T1 - Zur kristallchemie des ersten blei-zink-silicium-telluroxids

T2 - PbZn4SiTeO10

AU - Wedel, B.

AU - Sugiyama, K.

AU - Hiraga, K.

AU - Itagaki, K.

PY - 1999/4

Y1 - 1999/4

N2 - Single crystals of the new lead zinc silicon tellurium oxide PbZn4SiTeO10 have been prepared by solid state reaction in air. The compound is colourless and crystallizes in orthorhombic symmetry, space group D162h Pnma, with the cell parameters: a = 6.542 (5), b = 15.624(4), c = 8.280(4) Å, Z = 4. The structure has been determined from a single crystal X-ray study and refined to the conventional values R = 0.032 and wR(F2) = 0.050. Zn2+ and Si4+ show tetrahedral and Te6+ octahedral coordination by O2-.Thecrystal structurels dominated by a 3∞ [Zn4O10]12- framework with isolated TeO66+ and SiO44+ polyhedra. Pb2+ ions are incorporated in the network. The centres of negative charge of the lone pairs of Pb2+ are estimated by calculations of the Coulomb term of the lattice energy.

AB - Single crystals of the new lead zinc silicon tellurium oxide PbZn4SiTeO10 have been prepared by solid state reaction in air. The compound is colourless and crystallizes in orthorhombic symmetry, space group D162h Pnma, with the cell parameters: a = 6.542 (5), b = 15.624(4), c = 8.280(4) Å, Z = 4. The structure has been determined from a single crystal X-ray study and refined to the conventional values R = 0.032 and wR(F2) = 0.050. Zn2+ and Si4+ show tetrahedral and Te6+ octahedral coordination by O2-.Thecrystal structurels dominated by a 3∞ [Zn4O10]12- framework with isolated TeO66+ and SiO44+ polyhedra. Pb2+ ions are incorporated in the network. The centres of negative charge of the lone pairs of Pb2+ are estimated by calculations of the Coulomb term of the lattice energy.

KW - Crystal Structure

KW - Lead

KW - Silicon

KW - Tellurium

KW - Zinc

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