One-pot Claisen rearrangement with n-butyl vinyl ether

Hidetoshi Tokuyama; Takaki Makido; Toshihiro Ueda; Tohru Fukuyama

doi:10.1081/SCC-120002696

One-pot Claisen rearrangement with n-butyl vinyl ether

Hidetoshi Tokuyama, Takaki Makido, Toshihiro Ueda, Tohru Fukuyama

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

A protocol for one-pot Claisen rearrangement with n-butyl vinyl ether is described. Upon heating allylic alcohols with excess n-butyl vinyl ether with catalytic amount of Hg(OAc)₂ and NaOAc, Claisen rearrangement takes place through in situ formation of the requisite allyl vinyl ether.

Original language	English
Pages (from-to)	869-873
Number of pages	5
Journal	Synthetic Communications
Volume	32
Issue number	6
DOIs	https://doi.org/10.1081/SCC-120002696
Publication status	Published - 2002

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10.1081/SCC-120002696

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title = "One-pot Claisen rearrangement with n-butyl vinyl ether",

abstract = "A protocol for one-pot Claisen rearrangement with n-butyl vinyl ether is described. Upon heating allylic alcohols with excess n-butyl vinyl ether with catalytic amount of Hg(OAc)2 and NaOAc, Claisen rearrangement takes place through in situ formation of the requisite allyl vinyl ether.",

author = "Hidetoshi Tokuyama and Takaki Makido and Toshihiro Ueda and Tohru Fukuyama",

year = "2002",

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AU - Tokuyama, Hidetoshi

AU - Makido, Takaki

AU - Ueda, Toshihiro

AU - Fukuyama, Tohru

PY - 2002

Y1 - 2002

N2 - A protocol for one-pot Claisen rearrangement with n-butyl vinyl ether is described. Upon heating allylic alcohols with excess n-butyl vinyl ether with catalytic amount of Hg(OAc)2 and NaOAc, Claisen rearrangement takes place through in situ formation of the requisite allyl vinyl ether.

AB - A protocol for one-pot Claisen rearrangement with n-butyl vinyl ether is described. Upon heating allylic alcohols with excess n-butyl vinyl ether with catalytic amount of Hg(OAc)2 and NaOAc, Claisen rearrangement takes place through in situ formation of the requisite allyl vinyl ether.

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DO - 10.1081/SCC-120002696

M3 - Article

AN - SCOPUS:0036216729

SN - 0039-7911

VL - 32

SP - 869

EP - 873

JO - Synthetic Communications

JF - Synthetic Communications

IS - 6

ER -

One-pot Claisen rearrangement with n-butyl vinyl ether

Abstract

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