Organocatalytic asymmetric direct alkylation of α-diazoester via C-H bond cleavage

Daisuke Uraguchi; Keiichi Sorimachi; Masahiro Terada

doi:10.1021/ja051922a

Organocatalytic asymmetric direct alkylation of α-diazoester via C-H bond cleavage

Daisuke Uraguchi, Keiichi Sorimachi, Masahiro Terada

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

193 Citations (Scopus)

Abstract

A new variant of phosphoric acid-catalyzed C-C bond forming reaction, direct alkylation of α-diazoester, via C-H bond cleavage is presented. The resulting products, β-amino-α-diazoesters, are highly functionalized and useful synthetic precursors for various types of β-amino acids.

Original language	English
Pages (from-to)	9360-9361
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	127
Issue number	26
DOIs	https://doi.org/10.1021/ja051922a
Publication status	Published - 2005 Jul 6

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja051922a

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abstract = "A new variant of phosphoric acid-catalyzed C-C bond forming reaction, direct alkylation of α-diazoester, via C-H bond cleavage is presented. The resulting products, β-amino-α-diazoesters, are highly functionalized and useful synthetic precursors for various types of β-amino acids.",

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AU - Uraguchi, Daisuke

AU - Sorimachi, Keiichi

AU - Terada, Masahiro

PY - 2005/7/6

Y1 - 2005/7/6

N2 - A new variant of phosphoric acid-catalyzed C-C bond forming reaction, direct alkylation of α-diazoester, via C-H bond cleavage is presented. The resulting products, β-amino-α-diazoesters, are highly functionalized and useful synthetic precursors for various types of β-amino acids.

AB - A new variant of phosphoric acid-catalyzed C-C bond forming reaction, direct alkylation of α-diazoester, via C-H bond cleavage is presented. The resulting products, β-amino-α-diazoesters, are highly functionalized and useful synthetic precursors for various types of β-amino acids.

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M3 - Article

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Organocatalytic asymmetric direct alkylation of α-diazoester via C-H bond cleavage

Abstract

ASJC Scopus subject areas

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