Oxidation of a diphosphene and dechlorination of an arylphosphonic dichloride: Isolation of the diphosphene oxide

Masaaki Yoshifuji; Kaori Ando; Kozo Toyota; Ichiro Shima; Naoki Inamoto

doi:10.1039/c39830000419

Oxidation of a diphosphene and dechlorination of an arylphosphonic dichloride: Isolation of the diphosphene oxide

Masaaki Yoshifuji, Kaori Ando, Kozo Toyota, Ichiro Shima, Naoki Inamoto

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

The dechlorination reaction of the phosphonic dichloride ArP(O)Cl ₂ (Ar = 2,4,6-Bu^t₃C₆H₂) with magnesium gave the sterically protected diphosphene oxide ArP(O) = PAr as a stable compound.

Original language	English
Pages (from-to)	419-420
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/c39830000419
Publication status	Published - 1983 Jan 1
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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title = "Oxidation of a diphosphene and dechlorination of an arylphosphonic dichloride: Isolation of the diphosphene oxide",

abstract = "The dechlorination reaction of the phosphonic dichloride ArP(O)Cl 2 (Ar = 2,4,6-But3C6H2) with magnesium gave the sterically protected diphosphene oxide ArP(O) = PAr as a stable compound.",

author = "Masaaki Yoshifuji and Kaori Ando and Kozo Toyota and Ichiro Shima and Naoki Inamoto",

year = "1983",

month = jan,

day = "1",

doi = "10.1039/c39830000419",

language = "English",

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journal = "Chemical Communications",

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T1 - Oxidation of a diphosphene and dechlorination of an arylphosphonic dichloride

T2 - Isolation of the diphosphene oxide

AU - Yoshifuji, Masaaki

AU - Ando, Kaori

AU - Toyota, Kozo

AU - Shima, Ichiro

AU - Inamoto, Naoki

PY - 1983/1/1

Y1 - 1983/1/1

N2 - The dechlorination reaction of the phosphonic dichloride ArP(O)Cl 2 (Ar = 2,4,6-But3C6H2) with magnesium gave the sterically protected diphosphene oxide ArP(O) = PAr as a stable compound.

AB - The dechlorination reaction of the phosphonic dichloride ArP(O)Cl 2 (Ar = 2,4,6-But3C6H2) with magnesium gave the sterically protected diphosphene oxide ArP(O) = PAr as a stable compound.

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DO - 10.1039/c39830000419

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JF - Chemical Communications

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Oxidation of a diphosphene and dechlorination of an arylphosphonic dichloride: Isolation of the diphosphene oxide

Abstract

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