Oxidative conversion of silyl enol ethers to α,β-unsaturated ketones employing oxoammonium salts

Masaki Hayashi; Masatoshi Shibuya; Yoshiharu Iwabuchi

doi:10.1021/ol2029417

Oxidative conversion of silyl enol ethers to α,β-unsaturated ketones employing oxoammonium salts

Masaki Hayashi, Masatoshi Shibuya, Yoshiharu Iwabuchi

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

The oxidative conversion of silyl enol ethers to α,β-unsaturated ketones using a less-hindered class of oxoammonium salts (AZADO ⁺BF ₄ ^-) is described. The reaction proceeds via the ene-like addition of oxoammonium salts to silyl enol ethers.

Original language	English
Pages (from-to)	154-157
Number of pages	4
Journal	Organic Letters
Volume	14
Issue number	1
DOIs	https://doi.org/10.1021/ol2029417
Publication status	Published - 2012 Jan 6

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10.1021/ol2029417

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title = "Oxidative conversion of silyl enol ethers to α,β-unsaturated ketones employing oxoammonium salts",

abstract = "The oxidative conversion of silyl enol ethers to α,β-unsaturated ketones using a less-hindered class of oxoammonium salts (AZADO +BF 4 -) is described. The reaction proceeds via the ene-like addition of oxoammonium salts to silyl enol ethers.",

author = "Masaki Hayashi and Masatoshi Shibuya and Yoshiharu Iwabuchi",

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T1 - Oxidative conversion of silyl enol ethers to α,β-unsaturated ketones employing oxoammonium salts

AU - Hayashi, Masaki

AU - Shibuya, Masatoshi

AU - Iwabuchi, Yoshiharu

PY - 2012/1/6

Y1 - 2012/1/6

N2 - The oxidative conversion of silyl enol ethers to α,β-unsaturated ketones using a less-hindered class of oxoammonium salts (AZADO +BF 4 -) is described. The reaction proceeds via the ene-like addition of oxoammonium salts to silyl enol ethers.

AB - The oxidative conversion of silyl enol ethers to α,β-unsaturated ketones using a less-hindered class of oxoammonium salts (AZADO +BF 4 -) is described. The reaction proceeds via the ene-like addition of oxoammonium salts to silyl enol ethers.

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Oxidative conversion of silyl enol ethers to α,β-unsaturated ketones employing oxoammonium salts

Abstract

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