Oxidative dimerization of dimethyl ether with solid catalysts

Hiroshi Yagita; Kenji Asami; Atsushi Muramatsu; Kaoru Fujimoto

doi:10.1016/S0166-9834(00)80002-0

Oxidative dimerization of dimethyl ether with solid catalysts

Hiroshi Yagita, Kenji Asami, Atsushi Muramatsu, Kaoru Fujimoto

SRIS - SR Core Research Division

The University of Tokyo

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

It was found that the oxidative coupling of dimethyl ether (DME) to dimethoxyethane was catalyzed by SnO₂/MgO catalyst at around 200°C and 16 atm. The formation of 1,2-dimethoxyethane was favored for lower reaction temperatures, intermediate operating pressures and higher DME/O₂ ratios. The reaction mechanism for the supported tin catalyst system was assumed to be based on a redox cycle.

Original language	English
Pages (from-to)	L5-L9
Journal	Applied Catalysis
Volume	53
Issue number	1
DOIs	https://doi.org/10.1016/S0166-9834(00)80002-0
Publication status	Published - 1989

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title = "Oxidative dimerization of dimethyl ether with solid catalysts",

abstract = "It was found that the oxidative coupling of dimethyl ether (DME) to dimethoxyethane was catalyzed by SnO2/MgO catalyst at around 200°C and 16 atm. The formation of 1,2-dimethoxyethane was favored for lower reaction temperatures, intermediate operating pressures and higher DME/O2 ratios. The reaction mechanism for the supported tin catalyst system was assumed to be based on a redox cycle.",

author = "Hiroshi Yagita and Kenji Asami and Atsushi Muramatsu and Kaoru Fujimoto",

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T1 - Oxidative dimerization of dimethyl ether with solid catalysts

AU - Yagita, Hiroshi

AU - Asami, Kenji

AU - Muramatsu, Atsushi

AU - Fujimoto, Kaoru

PY - 1989

Y1 - 1989

N2 - It was found that the oxidative coupling of dimethyl ether (DME) to dimethoxyethane was catalyzed by SnO2/MgO catalyst at around 200°C and 16 atm. The formation of 1,2-dimethoxyethane was favored for lower reaction temperatures, intermediate operating pressures and higher DME/O2 ratios. The reaction mechanism for the supported tin catalyst system was assumed to be based on a redox cycle.

AB - It was found that the oxidative coupling of dimethyl ether (DME) to dimethoxyethane was catalyzed by SnO2/MgO catalyst at around 200°C and 16 atm. The formation of 1,2-dimethoxyethane was favored for lower reaction temperatures, intermediate operating pressures and higher DME/O2 ratios. The reaction mechanism for the supported tin catalyst system was assumed to be based on a redox cycle.

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DO - 10.1016/S0166-9834(00)80002-0

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JO - Applied Catalysis

JF - Applied Catalysis

IS - 1

ER -

Oxidative dimerization of dimethyl ether with solid catalysts

Abstract

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