TY - JOUR
T1 - P-coordinated group VI metal(0) pentacarbonyl complexes of multiple-bond organophosphorus compounds in the low coordination state
AU - Yoshifuji, Masaaki
AU - Shibayama, Katsuhiro
AU - Hashida, Takashi
AU - Toyota, Kozo
AU - Niitsu, Takashi
AU - Matsuda, Ikumi
AU - Sato, Takahiro
AU - Inamoto, Naoki
N1 - Funding Information:
This work was supported in part by the Scientific Research Grant-in-Aids from the Ministry of Education, Science and Culture of Japan and the Kurata Research Grant from the Kurata Foundation.
PY - 1986/9/9
Y1 - 1986/9/9
N2 - Group VI metal(0) carbonyl complexes of diphosphenes, phosphaethylenes, 1-phosphaallene, and 1,3-diphosphaallene with the phosphorus atom in the low coordination state were prepared, and the 31P chemical shifts of these complexes were found to correlate to one another: the structures in solution could be determined by taking into account the correlation and phosphorus-tungsten coupling constants in 31P NMR.
AB - Group VI metal(0) carbonyl complexes of diphosphenes, phosphaethylenes, 1-phosphaallene, and 1,3-diphosphaallene with the phosphorus atom in the low coordination state were prepared, and the 31P chemical shifts of these complexes were found to correlate to one another: the structures in solution could be determined by taking into account the correlation and phosphorus-tungsten coupling constants in 31P NMR.
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U2 - 10.1016/0022-328X(86)80269-8
DO - 10.1016/0022-328X(86)80269-8
M3 - Article
AN - SCOPUS:0002302693
SN - 0022-328X
VL - 311
SP - C63-C67
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 3
ER -