Palladium-catalyzed addition of silyl-substituted chloroalkynes to terminal alkynes

Tatsuya Wada, Masayuki Iwasaki, Azusa Kondoh, Hideki Yorimitsu, Koichiro Oshima

Research output: Contribution to journalArticlepeer-review

24 Citations (Scopus)


Better together: A novel hybrid N-heterocyclic carbene (NHC) palladium complex, integrating a totally inorganic and polyanionic decatungstate unit, has been synthesized following a convergent strategy. The interplay of the Pd binding domains with the inorganic scaffold is instrumental in accessing multi-turnover catalysis in C-C crosscoupling and aromatic dehalogenation reactions under MW-assisted protocols (see scheme). (Figure Presented)

Original languageEnglish
Pages (from-to)10671-10674
Number of pages4
JournalChemistry - A European Journal
Issue number35
Publication statusPublished - 2010 Sept 17


  • Addition reactions
  • Alkynes
  • Enynes
  • Palladium synthetic methods


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