Palladium-catalyzed anti-hydrothiolation of 1-alkynylphosphines

Azusa Kondoh; Hideki Yorimitsu; Koichiro Oshima

doi:10.1021/ol0702876

Palladium-catalyzed anti-hydrothiolation of 1-alkynylphosphines

Azusa Kondoh, Hideki Yorimitsu, Koichiro Oshima

SCI - Research and Analytical Center for Giant Molecules

Kyoto University

Research output: Contribution to journal › Article › peer-review

75 Citations (Scopus)

Abstract

Figure presented Treatment of 1-alkynylphosphine with thiol in the presence of a catalytic amount of palladium acetate results in regio- and stereoselective anti-hydrothiolation, yielding the corresponding (Z)-1-phosphino-2-thio-1-alkene.

Original language	English
Pages (from-to)	1383-1385
Number of pages	3
Journal	Organic Letters
Volume	9
Issue number	7
DOIs	https://doi.org/10.1021/ol0702876
Publication status	Published - 2007 Mar 29

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title = "Palladium-catalyzed anti-hydrothiolation of 1-alkynylphosphines",

abstract = "Figure presented Treatment of 1-alkynylphosphine with thiol in the presence of a catalytic amount of palladium acetate results in regio- and stereoselective anti-hydrothiolation, yielding the corresponding (Z)-1-phosphino-2-thio-1-alkene.",

author = "Azusa Kondoh and Hideki Yorimitsu and Koichiro Oshima",

year = "2007",

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doi = "10.1021/ol0702876",

language = "English",

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journal = "Organic Letters",

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T1 - Palladium-catalyzed anti-hydrothiolation of 1-alkynylphosphines

AU - Kondoh, Azusa

AU - Yorimitsu, Hideki

AU - Oshima, Koichiro

PY - 2007/3/29

Y1 - 2007/3/29

N2 - Figure presented Treatment of 1-alkynylphosphine with thiol in the presence of a catalytic amount of palladium acetate results in regio- and stereoselective anti-hydrothiolation, yielding the corresponding (Z)-1-phosphino-2-thio-1-alkene.

AB - Figure presented Treatment of 1-alkynylphosphine with thiol in the presence of a catalytic amount of palladium acetate results in regio- and stereoselective anti-hydrothiolation, yielding the corresponding (Z)-1-phosphino-2-thio-1-alkene.

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VL - 9

SP - 1383

EP - 1385

JO - Organic Letters

JF - Organic Letters

IS - 7

ER -

Palladium-catalyzed anti-hydrothiolation of 1-alkynylphosphines

Abstract

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