Palladium-catalyzed direct CH bond arylation of simple arenes with aryltrimethylsilanes

Kenji Funaki; Hiroshi Kawai; Tetsuo Sato; Shuichi Oi

doi:10.1246/cl.2011.1050

Palladium-catalyzed direct CH bond arylation of simple arenes with aryltrimethylsilanes

Kenji Funaki, Hiroshi Kawai, Tetsuo Sato, Shuichi Oi

New Industry Creation Hatchery Center (NICHe)

Research output: Contribution to journal › Article › peer-review

45 Citations (Scopus)

Abstract

Direct CH bond arylation of arenes with aryltrimethylsilanes catalyzed by PdCl₂ in the presence of CuCl₂ as an oxidant has been developed. In addition to the role as the oxidant, CuCl₂ is found to be necessary for the selective crosscoupling reaction.

Original language	English
Pages (from-to)	1050-1052
Number of pages	3
Journal	Chemistry Letters
Volume	40
Issue number	9
DOIs	https://doi.org/10.1246/cl.2011.1050
Publication status	Published - 2011

ASJC Scopus subject areas

Chemistry(all)

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10.1246/cl.2011.1050

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title = "Palladium-catalyzed direct CH bond arylation of simple arenes with aryltrimethylsilanes",

abstract = "Direct CH bond arylation of arenes with aryltrimethylsilanes catalyzed by PdCl2 in the presence of CuCl2 as an oxidant has been developed. In addition to the role as the oxidant, CuCl2 is found to be necessary for the selective crosscoupling reaction.",

author = "Kenji Funaki and Hiroshi Kawai and Tetsuo Sato and Shuichi Oi",

year = "2011",

doi = "10.1246/cl.2011.1050",

language = "English",

volume = "40",

pages = "1050--1052",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "9",

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T1 - Palladium-catalyzed direct CH bond arylation of simple arenes with aryltrimethylsilanes

AU - Funaki, Kenji

AU - Kawai, Hiroshi

AU - Sato, Tetsuo

AU - Oi, Shuichi

PY - 2011

Y1 - 2011

N2 - Direct CH bond arylation of arenes with aryltrimethylsilanes catalyzed by PdCl2 in the presence of CuCl2 as an oxidant has been developed. In addition to the role as the oxidant, CuCl2 is found to be necessary for the selective crosscoupling reaction.

AB - Direct CH bond arylation of arenes with aryltrimethylsilanes catalyzed by PdCl2 in the presence of CuCl2 as an oxidant has been developed. In addition to the role as the oxidant, CuCl2 is found to be necessary for the selective crosscoupling reaction.

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U2 - 10.1246/cl.2011.1050

DO - 10.1246/cl.2011.1050

M3 - Article

AN - SCOPUS:80052596565

SN - 0366-7022

VL - 40

SP - 1050

EP - 1052

JO - Chemistry Letters

JF - Chemistry Letters

IS - 9

ER -

Palladium-catalyzed direct CH bond arylation of simple arenes with aryltrimethylsilanes

Abstract

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