TY - JOUR
T1 - Palladium-catalyzed hydroalkoxylation of methylenecyclopropanes
AU - Camacho, Drexel H.
AU - Nakamura, Itaru
AU - Saito, Shinichi
AU - Yamamoto, Yoshinori
PY - 1999/11/15
Y1 - 1999/11/15
N2 - Hydroalkoxylations proceed by a different path than transition metal catalyzed hydrostannations and hydrosilylations. In the reaction of methylenecyclopropanes 1 with alcohols 2 in the presence of Pd°, the distal bond in the cyclopropane ring is cleaved, and allyl ether 3 is formed selectively. R1 = n- C7H15, PhCH2CH2; R2 = H, PhCH2CH2; R3 = PhCH2, CF3CH2, Et3Si, n-C4H9, etc.
AB - Hydroalkoxylations proceed by a different path than transition metal catalyzed hydrostannations and hydrosilylations. In the reaction of methylenecyclopropanes 1 with alcohols 2 in the presence of Pd°, the distal bond in the cyclopropane ring is cleaved, and allyl ether 3 is formed selectively. R1 = n- C7H15, PhCH2CH2; R2 = H, PhCH2CH2; R3 = PhCH2, CF3CH2, Et3Si, n-C4H9, etc.
KW - Alcohols
KW - Allyl ether formation
KW - Hydroalkoxylation reaction
KW - Methylenecyclopropanes
KW - Palladium
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U2 - 10.1002/(SICI)1521-3773(19991115)38:22<3365::AID-ANIE3365>3.0.CO;2-5
DO - 10.1002/(SICI)1521-3773(19991115)38:22<3365::AID-ANIE3365>3.0.CO;2-5
M3 - Article
AN - SCOPUS:0033571256
SN - 1433-7851
VL - 38
SP - 3365
EP - 3367
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 22
ER -