Partially-oxidized Ni(dmit)2 salt with copper ions

K. Sakai; T. Akutagawa; T. Hasegawa; T. Nakamura

doi:10.1016/S0379-6779(00)01047-X

Partially-oxidized Ni(dmit)₂ salt with copper ions

K. Sakai, T. Akutagawa, T. Hasegawa, T. Nakamura

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The d-π hybrid charge-transfer system, Cu_0.39[Ni(dmit)₂] was prepared, and the crystal and electronic band structures were investigated. In the crystal, a unique layered structure is constructed, which results from the stacks of dimerized Ni(dmit)₂ being largely slipped along the long molecular axis. The copper ions are located at the interlayer spaces with large thermal factors. From the tight-binding band calculation, a quasi-one-dimensional Fermi surface was obtained.

Original language	English
Pages (from-to)	805-806
Number of pages	2
Journal	Synthetic Metals
Volume	120
Issue number	1-3
DOIs	https://doi.org/10.1016/S0379-6779(00)01047-X
Publication status	Published - 2001 Mar 15
Externally published	Yes

Keywords

Diffraction and scattering
Organic conductors based on radical cation and/or anion salts
X-ray emission

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

Access to Document

10.1016/S0379-6779(00)01047-X

Cite this

@article{e9892738b29d4ec69688b249409418a6,

title = "Partially-oxidized Ni(dmit)2 salt with copper ions",

abstract = "The d-π hybrid charge-transfer system, Cu0.39[Ni(dmit)2] was prepared, and the crystal and electronic band structures were investigated. In the crystal, a unique layered structure is constructed, which results from the stacks of dimerized Ni(dmit)2 being largely slipped along the long molecular axis. The copper ions are located at the interlayer spaces with large thermal factors. From the tight-binding band calculation, a quasi-one-dimensional Fermi surface was obtained.",

keywords = "Diffraction and scattering, Organic conductors based on radical cation and/or anion salts, X-ray emission",

author = "K. Sakai and T. Akutagawa and T. Hasegawa and T. Nakamura",

year = "2001",

month = mar,

day = "15",

doi = "10.1016/S0379-6779(00)01047-X",

language = "English",

volume = "120",

pages = "805--806",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier BV",

number = "1-3",

}

TY - JOUR

T1 - Partially-oxidized Ni(dmit)2 salt with copper ions

AU - Sakai, K.

AU - Akutagawa, T.

AU - Hasegawa, T.

AU - Nakamura, T.

PY - 2001/3/15

Y1 - 2001/3/15

N2 - The d-π hybrid charge-transfer system, Cu0.39[Ni(dmit)2] was prepared, and the crystal and electronic band structures were investigated. In the crystal, a unique layered structure is constructed, which results from the stacks of dimerized Ni(dmit)2 being largely slipped along the long molecular axis. The copper ions are located at the interlayer spaces with large thermal factors. From the tight-binding band calculation, a quasi-one-dimensional Fermi surface was obtained.

AB - The d-π hybrid charge-transfer system, Cu0.39[Ni(dmit)2] was prepared, and the crystal and electronic band structures were investigated. In the crystal, a unique layered structure is constructed, which results from the stacks of dimerized Ni(dmit)2 being largely slipped along the long molecular axis. The copper ions are located at the interlayer spaces with large thermal factors. From the tight-binding band calculation, a quasi-one-dimensional Fermi surface was obtained.

KW - Diffraction and scattering

KW - Organic conductors based on radical cation and/or anion salts

KW - X-ray emission

UR - http://www.scopus.com/inward/record.url?scp=0035867973&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035867973&partnerID=8YFLogxK

U2 - 10.1016/S0379-6779(00)01047-X

DO - 10.1016/S0379-6779(00)01047-X

M3 - Article

AN - SCOPUS:0035867973

SN - 0379-6779

VL - 120

SP - 805

EP - 806

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1-3

ER -