TY - JOUR
T1 - Pentaamminechlorogallium(III) dichloride
AU - Yamane, Hisanori
AU - Mikawa, Yutaka
AU - Yokoyama, Chiaki
PY - 2007/2
Y1 - 2007/2
N2 - Crystals of the title compound, [Ga(NH3)5Cl]Cl 2, were prepared from 1-butyl-3-methylimidazolium chloride and GaCl3. The crystal structure is isotypic with [Al(NH 3)5Cl]Cl2 and other members of the series [M(NH3)5Cl]Cl2, with M = Cr, Co, Rh, Ir, Ru or Os. It consists of discrete cationic [Ga(NH3)5Cl] 2+ octahedra and Cl- anions arranged in motifs related to the K2PtCl6 structure type. In the cation, the Ga atom, one Cl atom and three N atoms are located on a mirror plane.
AB - Crystals of the title compound, [Ga(NH3)5Cl]Cl 2, were prepared from 1-butyl-3-methylimidazolium chloride and GaCl3. The crystal structure is isotypic with [Al(NH 3)5Cl]Cl2 and other members of the series [M(NH3)5Cl]Cl2, with M = Cr, Co, Rh, Ir, Ru or Os. It consists of discrete cationic [Ga(NH3)5Cl] 2+ octahedra and Cl- anions arranged in motifs related to the K2PtCl6 structure type. In the cation, the Ga atom, one Cl atom and three N atoms are located on a mirror plane.
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U2 - 10.1107/S1600536807003388
DO - 10.1107/S1600536807003388
M3 - Article
AN - SCOPUS:33846963826
SN - 1600-5368
VL - 63
SP - i59-i61
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 2
ER -