TY - JOUR
T1 - Perfluoroacylation of alkenes
AU - Nenajdenko, Valentine G.
AU - Gridnev, Ilya D.
AU - Balenkova, Elizabeth S.
N1 - Funding Information:
Acknowledgements:T he researchd escribedi n this publication was made possible in part by Grant M-29000 from the International Science Foundation, Grant N 94-03-08758f rom Russian Fundamental Investigation Foundation.
PY - 1994
Y1 - 1994
N2 - Reaction of direct electrophilic perfluoroacylation of different structure alkenes with trifluoroacetic anhydride activated by BF3 · SMe2 complex leads to trifluoromethylalkenylketones with different structure of alkenyl group. Possible composition of the reactive species is considered on the basis of IR and NMR data. Dependence of the reaction course on the substrate structure is discussed.
AB - Reaction of direct electrophilic perfluoroacylation of different structure alkenes with trifluoroacetic anhydride activated by BF3 · SMe2 complex leads to trifluoromethylalkenylketones with different structure of alkenyl group. Possible composition of the reactive species is considered on the basis of IR and NMR data. Dependence of the reaction course on the substrate structure is discussed.
KW - boron trifluoride dimethyl sulfide complex
KW - electrophilic perfluoroacylation
KW - perfluorinated group
KW - sulfonium salt
KW - trifluoroacetic anhydride
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U2 - 10.1016/S0040-4020(01)85712-4
DO - 10.1016/S0040-4020(01)85712-4
M3 - Article
AN - SCOPUS:0028025497
SN - 0040-4020
VL - 50
SP - 11023
EP - 11038
JO - Tetrahedron
JF - Tetrahedron
IS - 37
ER -