Phase-controlled supramolecular photochirogenesis in cyclodextrin nanosponges

Wenting Liang; Cheng Yang; Dayang Zhou; Hitoshi Haneoka; Masaki Nishijima; Gaku Fukuhara; Tadashi Mori; Franca Castiglione; Andrea Mele; Fabrizio Caldera; Francesco Trotta; Yoshihisa Inoue

doi:10.1039/c3cc40542g

Phase-controlled supramolecular photochirogenesis in cyclodextrin nanosponges

Wenting Liang, Cheng Yang, Dayang Zhou, Hitoshi Haneoka, Masaki Nishijima, Gaku Fukuhara, Tadashi Mori, Franca Castiglione, Andrea Mele, Fabrizio Caldera, Francesco Trotta, Yoshihisa Inoue

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

Pyromellitate-bridged cyclodextrin nanosponges (CDNSs) evolved from sol into gel state upon gradual increase of the concentration from 0.2 to 2000 mg mL⁻¹ in water. The enantiodifferentiating geometrical photoisomerizations of (Z)-cyclooctene and (Z, Z)-1,3-cyclooctadiene sensitized by CDNS at various concentrations were critically affected by the phase transition of CDNS to afford the corresponding (E)- and (E, Z)-isomers in the highest enantiomeric excesses in the gel state.

Original language	English
Pages (from-to)	3510-3512
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	34
DOIs	https://doi.org/10.1039/c3cc40542g
Publication status	Published - 2013 Apr 2
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Phase-controlled supramolecular photochirogenesis in cyclodextrin nanosponges",

abstract = "Pyromellitate-bridged cyclodextrin nanosponges (CDNSs) evolved from sol into gel state upon gradual increase of the concentration from 0.2 to 2000 mg mL−1 in water. The enantiodifferentiating geometrical photoisomerizations of (Z)-cyclooctene and (Z, Z)-1,3-cyclooctadiene sensitized by CDNS at various concentrations were critically affected by the phase transition of CDNS to afford the corresponding (E)- and (E, Z)-isomers in the highest enantiomeric excesses in the gel state.",

author = "Wenting Liang and Cheng Yang and Dayang Zhou and Hitoshi Haneoka and Masaki Nishijima and Gaku Fukuhara and Tadashi Mori and Franca Castiglione and Andrea Mele and Fabrizio Caldera and Francesco Trotta and Yoshihisa Inoue",

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T1 - Phase-controlled supramolecular photochirogenesis in cyclodextrin nanosponges

AU - Liang, Wenting

AU - Yang, Cheng

AU - Zhou, Dayang

AU - Haneoka, Hitoshi

AU - Nishijima, Masaki

AU - Fukuhara, Gaku

AU - Mori, Tadashi

AU - Castiglione, Franca

AU - Mele, Andrea

AU - Caldera, Fabrizio

AU - Trotta, Francesco

AU - Inoue, Yoshihisa

PY - 2013/4/2

Y1 - 2013/4/2

N2 - Pyromellitate-bridged cyclodextrin nanosponges (CDNSs) evolved from sol into gel state upon gradual increase of the concentration from 0.2 to 2000 mg mL−1 in water. The enantiodifferentiating geometrical photoisomerizations of (Z)-cyclooctene and (Z, Z)-1,3-cyclooctadiene sensitized by CDNS at various concentrations were critically affected by the phase transition of CDNS to afford the corresponding (E)- and (E, Z)-isomers in the highest enantiomeric excesses in the gel state.

AB - Pyromellitate-bridged cyclodextrin nanosponges (CDNSs) evolved from sol into gel state upon gradual increase of the concentration from 0.2 to 2000 mg mL−1 in water. The enantiodifferentiating geometrical photoisomerizations of (Z)-cyclooctene and (Z, Z)-1,3-cyclooctadiene sensitized by CDNS at various concentrations were critically affected by the phase transition of CDNS to afford the corresponding (E)- and (E, Z)-isomers in the highest enantiomeric excesses in the gel state.

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JO - Chemical Communications

JF - Chemical Communications

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Phase-controlled supramolecular photochirogenesis in cyclodextrin nanosponges

Abstract

ASJC Scopus subject areas

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