TY - JOUR
T1 - Phase-field investigation of the coarsening of porous structures by surface diffusion
AU - Geslin, Pierre Antoine
AU - Buchet, Mickaël
AU - Wada, Takeshi
AU - Kato, Hidemi
N1 - Funding Information:
The authors would like to gratefully thank Morgane Mokhtari, Christophe Le Bourlot, and Eric Maire for supplying the x-ray tomographic structures discussed in Sec. V . P.A.G. would also like to personally thank Tetsuo Mohri (IMR, Tohoku Univesrity) for fruitful discussion on this work. Also P.A.G. gratefully acknowledges SR16000 supercomputing resources from the Center for Computational Materials Science of the Institute for Materials Research, Tohoku University.
Publisher Copyright:
© 2019 American Physical Society.
PY - 2019/8/8
Y1 - 2019/8/8
N2 - Nano and microporous connected structures have attracted increasing attention in the past decades due to their high surface area, presenting interesting properties for a number of applications. These structures generally coarsen by surface diffusion, leading to an enlargement of the structure characteristic length scale. We propose to study this coarsening behavior using a phase-field model for surface diffusion. In addition to reproducing the expected scaling law, our simulations enable to investigate precisely the evolution of the topological and morphological characteristics along the coarsening process. In particular, we show that after a transient regime, the coarsening is self-similar as exhibited by the evolution of both morphological and topological features. In addition, the influence of surface anisotropy is discussed and comparisons with experimental tomographic observations are presented.
AB - Nano and microporous connected structures have attracted increasing attention in the past decades due to their high surface area, presenting interesting properties for a number of applications. These structures generally coarsen by surface diffusion, leading to an enlargement of the structure characteristic length scale. We propose to study this coarsening behavior using a phase-field model for surface diffusion. In addition to reproducing the expected scaling law, our simulations enable to investigate precisely the evolution of the topological and morphological characteristics along the coarsening process. In particular, we show that after a transient regime, the coarsening is self-similar as exhibited by the evolution of both morphological and topological features. In addition, the influence of surface anisotropy is discussed and comparisons with experimental tomographic observations are presented.
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U2 - 10.1103/PhysRevMaterials.3.083401
DO - 10.1103/PhysRevMaterials.3.083401
M3 - Article
AN - SCOPUS:85070541413
SN - 2475-9953
VL - 3
JO - Physical Review Materials
JF - Physical Review Materials
IS - 8
M1 - 083401
ER -