Photochemistry of a Tellurosilyl(carbonyl)iron(II) Complex. Generation of a Novel Te-Si-Fe Three-membered Cyclic Intermediate

Hiroshi Okada; Masaaki Okazaki; Hiromi Tobita; Hiroshi Ogino

doi:10.1246/cl.2003.876

Photochemistry of a Tellurosilyl(carbonyl)iron(II) Complex. Generation of a Novel Te-Si-Fe Three-membered Cyclic Intermediate

Hiroshi Okada, Masaaki Okazaki, Hiromi Tobita, Hiroshi Ogino

IEHE - Institute for Excellence in Higher Education (organization affiliation only)

Tohoku University

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The tellurosilyliron complex Cp*(CO)₂FeSiMe ₂TePh (1) was synthesized by treatment of Cp*(CO) ₂FeSiMe₂Cl with LiTePh. Irradiation of complex 1 and acetone in toluene led to dissociation of a CO ligand and insertion of acetone into the silicon-tellurium bond to afford the five-membered metallacycle Cp*(CO)Fe{K²(Si,Te)-Me₂SiOCMe₂TePh}.

Original language	English
Pages (from-to)	876-877
Number of pages	2
Journal	Chemistry Letters
Volume	32
Issue number	9
DOIs	https://doi.org/10.1246/cl.2003.876
Publication status	Published - 2003 Sept 5

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10.1246/cl.2003.876

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title = "Photochemistry of a Tellurosilyl(carbonyl)iron(II) Complex. Generation of a Novel Te-Si-Fe Three-membered Cyclic Intermediate",

abstract = "The tellurosilyliron complex Cp*(CO)2FeSiMe 2TePh (1) was synthesized by treatment of Cp*(CO) 2FeSiMe2Cl with LiTePh. Irradiation of complex 1 and acetone in toluene led to dissociation of a CO ligand and insertion of acetone into the silicon-tellurium bond to afford the five-membered metallacycle Cp*(CO)Fe{K2(Si,Te)-Me2SiOCMe2TePh}.",

author = "Hiroshi Okada and Masaaki Okazaki and Hiromi Tobita and Hiroshi Ogino",

year = "2003",

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doi = "10.1246/cl.2003.876",

language = "English",

volume = "32",

pages = "876--877",

journal = "Chemistry Letters",

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T1 - Photochemistry of a Tellurosilyl(carbonyl)iron(II) Complex. Generation of a Novel Te-Si-Fe Three-membered Cyclic Intermediate

AU - Okada, Hiroshi

AU - Okazaki, Masaaki

AU - Tobita, Hiromi

AU - Ogino, Hiroshi

PY - 2003/9/5

Y1 - 2003/9/5

N2 - The tellurosilyliron complex Cp*(CO)2FeSiMe 2TePh (1) was synthesized by treatment of Cp*(CO) 2FeSiMe2Cl with LiTePh. Irradiation of complex 1 and acetone in toluene led to dissociation of a CO ligand and insertion of acetone into the silicon-tellurium bond to afford the five-membered metallacycle Cp*(CO)Fe{K2(Si,Te)-Me2SiOCMe2TePh}.

AB - The tellurosilyliron complex Cp*(CO)2FeSiMe 2TePh (1) was synthesized by treatment of Cp*(CO) 2FeSiMe2Cl with LiTePh. Irradiation of complex 1 and acetone in toluene led to dissociation of a CO ligand and insertion of acetone into the silicon-tellurium bond to afford the five-membered metallacycle Cp*(CO)Fe{K2(Si,Te)-Me2SiOCMe2TePh}.

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DO - 10.1246/cl.2003.876

M3 - Article

AN - SCOPUS:0346120348

SN - 0366-7022

VL - 32

SP - 876

EP - 877

JO - Chemistry Letters

JF - Chemistry Letters

IS - 9

ER -

Photochemistry of a Tellurosilyl(carbonyl)iron(II) Complex. Generation of a Novel Te-Si-Fe Three-membered Cyclic Intermediate

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