## Abstract

Clusters of Mg^{+} with AN molecules, Mg(AN)_{n}^{+}, were investigated by photodissociation spectroscopy and theoretical calculations. In the dissociation spectrum of n=1, two absorption bands were observed at 26 400 and 40 800 cm^{-1}. On the other hand, three absorption bands centered at 22 600, 28 800, and 37 500 cm^{-1} appeared for n=2. These absorption bands were assigned by using DFT(B3LYP/6-31+G*) and CIS/6-31+G* methods.

Original language | English |
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Pages (from-to) | 5456-5464 |

Number of pages | 9 |

Journal | Journal of Chemical Physics |

Volume | 118 |

Issue number | 12 |

DOIs | |

Publication status | Published - 2003 Mar 22 |

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_{n}

^{+}: Excited electronic states of n = 1 and 2 and intracluster electron transfer for n = 3 and 4'. Together they form a unique fingerprint.