TY - JOUR
T1 - Photoexcitable polymer membranes. Photoinduced membrane potential across poly(vinyl chloride) membrane doped with a photosensitive crown ether having lipophilic side chain
AU - Anzai, Jun‐Ichi ‐I
AU - Hasebe, Yasushi
AU - Ueno, Akihiko
AU - Osa, Tetsuo
PY - 1988/6
Y1 - 1988/6
N2 - Photoirradiation induced potential changes of 10–20 mV across the poly(vinyl chloride) membranes doped with a photosensitive lipophilic crown ether, p‐[3,4‐(1,4,7,10,13‐pentaoxatridecane‐1,13‐diyl)phenylazo]hexadecyloxybenzene was studied. The photoresponse of the membrane was highly improved, presumably due to the lipophilic nature of the crown ether. The photoresponse was explained in terms of the charge density change on the membrane surface. The electric double layer theory was applied to estimate the values of the photoinduced change of the charge density.
AB - Photoirradiation induced potential changes of 10–20 mV across the poly(vinyl chloride) membranes doped with a photosensitive lipophilic crown ether, p‐[3,4‐(1,4,7,10,13‐pentaoxatridecane‐1,13‐diyl)phenylazo]hexadecyloxybenzene was studied. The photoresponse of the membrane was highly improved, presumably due to the lipophilic nature of the crown ether. The photoresponse was explained in terms of the charge density change on the membrane surface. The electric double layer theory was applied to estimate the values of the photoinduced change of the charge density.
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U2 - 10.1002/pola.1988.080260603
DO - 10.1002/pola.1988.080260603
M3 - Article
AN - SCOPUS:0024034423
SN - 0887-624X
VL - 26
SP - 1519
EP - 1529
JO - Journal of Polymer Science, Part A: Polymer Chemistry
JF - Journal of Polymer Science, Part A: Polymer Chemistry
IS - 6
ER -