Physical properties of quasi-one-dimensional mixed-metal and mixed-halogen complexese, Ni1-xPdx (chxn)2Cl yBr1-yY2

Toshio Manabe, Kouhei Yokoyama, Tomohiko Ishii, Hitoshi Miyasaka, Hiroyuki Matsuzaka, Masahiro Yamashita, Takuya Kawashima, Hiroyuki Matsuzaki, Hideo Kishida, Hiroshi Okamoto, Kazuhiro Marumoto, Hisaaki Tanaka, Hiroshi Itoh, Sin Ichi Kuroda

Research output: Contribution to journalConference articlepeer-review


A series of single crystals of quasi-one-dimensional Ni-Pd mixed-metal MX-chain compounds, Ni1-xPdx(chxn)2Br 3, and mixed-halogen MX-chain compounds, Ni(chxn)2Cl yBr1-y(NO3)2 have been obtained by electrochemical oxidation methods. In order to investigate the electronic states of these compounds, the optical conductivity spectra have been measured. These results indicate that the electronic states of the Ni compounds can be controlled by forming the mixed-metal or mixed-halogen systems.

Original languageEnglish
Pages (from-to)165-170
Number of pages6
JournalMolecular Crystals and Liquid Crystals
Publication statusPublished - 2002
EventProceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids - Honolulu, HI, United States
Duration: 2000 Dec 152000 Dec 18


  • Electron correlation
  • Halogen bridged complexes
  • Reflection spectroscopy


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