Physical properties of quasi-one-dimensional mixed-metal and mixed-halogen complexese, Ni1-xPdx (chxn)2Cl yBr1-yY2

Toshio Manabe; Kouhei Yokoyama; Tomohiko Ishii; Hitoshi Miyasaka; Hiroyuki Matsuzaka; Masahiro Yamashita; Takuya Kawashima; Hiroyuki Matsuzaki; Hideo Kishida; Hiroshi Okamoto; Kazuhiro Marumoto; Hisaaki Tanaka; Hiroshi Itoh; Sin Ichi Kuroda

doi:10.1080/10587250210772

Physical properties of quasi-one-dimensional mixed-metal and mixed-halogen complexese, Ni_1-xPd_x (chxn)₂Cl _yBr_1-yY₂

Toshio Manabe, Kouhei Yokoyama, Tomohiko Ishii, Hitoshi Miyasaka, Hiroyuki Matsuzaka, Masahiro Yamashita, Takuya Kawashima, Hiroyuki Matsuzaki, Hideo Kishida, Hiroshi Okamoto, Kazuhiro Marumoto, Hisaaki Tanaka, Hiroshi Itoh, Sin Ichi Kuroda

IMR - Materials Development Division

Research output: Contribution to journal › Conference article › peer-review

Abstract

A series of single crystals of quasi-one-dimensional Ni-Pd mixed-metal MX-chain compounds, Ni_1-xPd_x(chxn)₂Br ₃, and mixed-halogen MX-chain compounds, Ni(chxn)₂Cl _yBr_1-y(NO₃)₂ have been obtained by electrochemical oxidation methods. In order to investigate the electronic states of these compounds, the optical conductivity spectra have been measured. These results indicate that the electronic states of the Ni compounds can be controlled by forming the mixed-metal or mixed-halogen systems.

Original language	English
Pages (from-to)	165-170
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals
Volume	376
DOIs	https://doi.org/10.1080/10587250210772
Publication status	Published - 2002
Event	Proceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids - Honolulu, HI, United States Duration: 2000 Dec 15 → 2000 Dec 18

Keywords

Electron correlation
Halogen bridged complexes
Reflection spectroscopy

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10.1080/10587250210772

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Manabe, T., Yokoyama, K., Ishii, T., Miyasaka, H., Matsuzaka, H., Yamashita, M., Kawashima, T., Matsuzaki, H., Kishida, H., Okamoto, H., Marumoto, K., Tanaka, H., Itoh, H., & Kuroda, S. I. (2002). Physical properties of quasi-one-dimensional mixed-metal and mixed-halogen complexese, Ni_1-xPd_x (chxn)₂Cl _yBr_1-yY₂. Molecular Crystals and Liquid Crystals, 376, 165-170. https://doi.org/10.1080/10587250210772

@article{18dd27cdc41d4b02a699dccf1301aa3c,

title = "Physical properties of quasi-one-dimensional mixed-metal and mixed-halogen complexese, Ni1-xPdx (chxn)2Cl yBr1-yY2",

abstract = "A series of single crystals of quasi-one-dimensional Ni-Pd mixed-metal MX-chain compounds, Ni1-xPdx(chxn)2Br 3, and mixed-halogen MX-chain compounds, Ni(chxn)2Cl yBr1-y(NO3)2 have been obtained by electrochemical oxidation methods. In order to investigate the electronic states of these compounds, the optical conductivity spectra have been measured. These results indicate that the electronic states of the Ni compounds can be controlled by forming the mixed-metal or mixed-halogen systems.",

keywords = "Electron correlation, Halogen bridged complexes, Reflection spectroscopy",

author = "Toshio Manabe and Kouhei Yokoyama and Tomohiko Ishii and Hitoshi Miyasaka and Hiroyuki Matsuzaka and Masahiro Yamashita and Takuya Kawashima and Hiroyuki Matsuzaki and Hideo Kishida and Hiroshi Okamoto and Kazuhiro Marumoto and Hisaaki Tanaka and Hiroshi Itoh and Kuroda, {Sin Ichi}",

year = "2002",

doi = "10.1080/10587250210772",

language = "English",

volume = "376",

pages = "165--170",

journal = "Molecular Crystals and Liquid Crystals",

issn = "1058-725X",

publisher = "Taylor and Francis Ltd.",

note = "Proceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids ; Conference date: 15-12-2000 Through 18-12-2000",

}

Manabe, T, Yokoyama, K, Ishii, T, Miyasaka, H, Matsuzaka, H, Yamashita, M, Kawashima, T, Matsuzaki, H, Kishida, H, Okamoto, H, Marumoto, K, Tanaka, H, Itoh, H & Kuroda, SI 2002, 'Physical properties of quasi-one-dimensional mixed-metal and mixed-halogen complexese, Ni_1-xPd_x (chxn)₂Cl _yBr_1-yY₂', Molecular Crystals and Liquid Crystals, vol. 376, pp. 165-170. https://doi.org/10.1080/10587250210772

TY - JOUR

T1 - Physical properties of quasi-one-dimensional mixed-metal and mixed-halogen complexese, Ni1-xPdx (chxn)2Cl yBr1-yY2

AU - Manabe, Toshio

AU - Yokoyama, Kouhei

AU - Ishii, Tomohiko

AU - Miyasaka, Hitoshi

AU - Matsuzaka, Hiroyuki

AU - Yamashita, Masahiro

AU - Kawashima, Takuya

AU - Matsuzaki, Hiroyuki

AU - Kishida, Hideo

AU - Okamoto, Hiroshi

AU - Marumoto, Kazuhiro

AU - Tanaka, Hisaaki

AU - Itoh, Hiroshi

AU - Kuroda, Sin Ichi

PY - 2002

Y1 - 2002

N2 - A series of single crystals of quasi-one-dimensional Ni-Pd mixed-metal MX-chain compounds, Ni1-xPdx(chxn)2Br 3, and mixed-halogen MX-chain compounds, Ni(chxn)2Cl yBr1-y(NO3)2 have been obtained by electrochemical oxidation methods. In order to investigate the electronic states of these compounds, the optical conductivity spectra have been measured. These results indicate that the electronic states of the Ni compounds can be controlled by forming the mixed-metal or mixed-halogen systems.

AB - A series of single crystals of quasi-one-dimensional Ni-Pd mixed-metal MX-chain compounds, Ni1-xPdx(chxn)2Br 3, and mixed-halogen MX-chain compounds, Ni(chxn)2Cl yBr1-y(NO3)2 have been obtained by electrochemical oxidation methods. In order to investigate the electronic states of these compounds, the optical conductivity spectra have been measured. These results indicate that the electronic states of the Ni compounds can be controlled by forming the mixed-metal or mixed-halogen systems.

KW - Electron correlation

KW - Halogen bridged complexes

KW - Reflection spectroscopy

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U2 - 10.1080/10587250210772

DO - 10.1080/10587250210772

M3 - Conference article

AN - SCOPUS:19944398734

SN - 1058-725X

VL - 376

SP - 165

EP - 170

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

T2 - Proceedings of the Interdisciplinary Symposium on Multifunctionality of Inorganic , Organic, and Their Hybrid Solids

Y2 - 15 December 2000 through 18 December 2000

ER -

Physical properties of quasi-one-dimensional mixed-metal and mixed-halogen complexese, Ni_1-xPd_x (chxn)₂Cl _yBr_1-yY₂

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