TY - JOUR
T1 - Pincer-type bis(carbene)-derived complexes of nickel(II)
T2 - Synthesis, structure, and catalytic activity
AU - Inamoto, Kiyofumi
AU - Kuroda, Jun ichi
AU - Kwon, Eunsang
AU - Hiroya, Kou
AU - Doi, Takayuki
N1 - Funding Information:
This work was supported in part by a Grant-in-Aid for JSPS Fellows from the Japan Society for the Promotion of Science (JSPS).
PY - 2009/2/1
Y1 - 2009/2/1
N2 - Air- and moisture-stable NHC (N-heterocyclic carbene)-derived CNC-type pincer complexes of nickel(II) 4a-d were successfully synthesized, and their structures were fully characterized using X-ray crystallography and analytical and spectroscopic methods. These complexes exhibit a high catalytic activity for the Suzuki-Miyaura coupling reaction of aryl bromides and chlorides with aryl- and alkenylboronic acids, providing an array of biphenyls and stilbenes generally in high yields.
AB - Air- and moisture-stable NHC (N-heterocyclic carbene)-derived CNC-type pincer complexes of nickel(II) 4a-d were successfully synthesized, and their structures were fully characterized using X-ray crystallography and analytical and spectroscopic methods. These complexes exhibit a high catalytic activity for the Suzuki-Miyaura coupling reaction of aryl bromides and chlorides with aryl- and alkenylboronic acids, providing an array of biphenyls and stilbenes generally in high yields.
KW - N-heterocyclic carbene
KW - Nickel
KW - Pincer complex
KW - Suzuki-Miyaura coupling
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U2 - 10.1016/j.jorganchem.2008.11.003
DO - 10.1016/j.jorganchem.2008.11.003
M3 - Article
AN - SCOPUS:58149503755
SN - 0022-328X
VL - 694
SP - 389
EP - 396
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 3
ER -