Platinum- and palladium-catalyzed sequential reactions: Regioselective synthesis of 9-fluorenylidenes from 9-ethynylfluoren-9-yl carboxylates and furans

Koji Miki; Yoshinori Senda; Toshiyuki Kowada; Kouichi Ohe

doi:10.1055/s-0029-1217531

Platinum- and palladium-catalyzed sequential reactions: Regioselective synthesis of 9-fluorenylidenes from 9-ethynylfluoren-9-yl carboxylates and furans

Koji Miki, Yoshinori Senda, Toshiyuki Kowada, Kouichi Ohe

IMRAM - Division of Organic- and Biomaterials Research

Kyoto University

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The transformation of 9-acyloxy-9-ethynylfluorene and furans with platinum and palladium co-catalysts gave 9-fluorenylidenes in excellent yields with high regioselectivity in a one-pot manner.

Original language	English
Pages (from-to)	1937-1940
Number of pages	4
Journal	Synlett
Issue number	12
DOIs	https://doi.org/10.1055/s-0029-1217531
Publication status	Published - 2009 Jul

Keywords

Carbene
Fluorene
Palladium
Platinum
Ring opening

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title = "Platinum- and palladium-catalyzed sequential reactions: Regioselective synthesis of 9-fluorenylidenes from 9-ethynylfluoren-9-yl carboxylates and furans",

abstract = "The transformation of 9-acyloxy-9-ethynylfluorene and furans with platinum and palladium co-catalysts gave 9-fluorenylidenes in excellent yields with high regioselectivity in a one-pot manner.",

keywords = "Carbene, Fluorene, Palladium, Platinum, Ring opening",

author = "Koji Miki and Yoshinori Senda and Toshiyuki Kowada and Kouichi Ohe",

year = "2009",

month = jul,

doi = "10.1055/s-0029-1217531",

language = "English",

pages = "1937--1940",

journal = "Synlett",

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publisher = "Georg Thieme Verlag",

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T2 - Regioselective synthesis of 9-fluorenylidenes from 9-ethynylfluoren-9-yl carboxylates and furans

AU - Miki, Koji

AU - Senda, Yoshinori

AU - Kowada, Toshiyuki

AU - Ohe, Kouichi

PY - 2009/7

Y1 - 2009/7

N2 - The transformation of 9-acyloxy-9-ethynylfluorene and furans with platinum and palladium co-catalysts gave 9-fluorenylidenes in excellent yields with high regioselectivity in a one-pot manner.

AB - The transformation of 9-acyloxy-9-ethynylfluorene and furans with platinum and palladium co-catalysts gave 9-fluorenylidenes in excellent yields with high regioselectivity in a one-pot manner.

KW - Carbene

KW - Fluorene

KW - Palladium

KW - Platinum

KW - Ring opening

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DO - 10.1055/s-0029-1217531

M3 - Article

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SN - 0936-5214

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IS - 12

ER -

Platinum- and palladium-catalyzed sequential reactions: Regioselective synthesis of 9-fluorenylidenes from 9-ethynylfluoren-9-yl carboxylates and furans

Abstract

Keywords

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