Polyoxometalate-based frameworks with a linker of paddlewheel diruthenium(ii, iii) complexes

Akihiro Hashikawa; Yuki Sawada; Yuma Yamamoto; Masaki Nishio; Wataru Kosaka; Yoshihito Hayashi; Hitoshi Miyasaka

doi:10.1039/c3ce40426a

Polyoxometalate-based frameworks with a linker of paddlewheel diruthenium(ii, iii) complexes

Akihiro Hashikawa, Yuki Sawada, Yuma Yamamoto, Masaki Nishio, Wataru Kosaka, Yoshihito Hayashi, Hitoshi Miyasaka

Materials Development Division

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The assembly reactions of a pivalate-bridged paddlewheel diruthenium(ii, iii) complex, [Ru₂^II,III(piv)₄(THF) ₂]BF₄ (piv = pivalate), with three types of polyoxometalate (POM) clusters, (TBA)₂[Mo₆O₁₉] (TBA = tetra-n-butylammonium cation; Lindqvist-type Mo₆ POM), (TBA)₃[H₃V₁₀O₂₈] (V ₁₀-type POM), and (THA)₃[PMo₁₂O₄₀] (THA = tetra-n-hexylammonium cation; Keggin-type Mo₁₂ POM), led successfully to the formation of one-, two-, and three-dimensional (1-, 2-, and 3-D) frameworks composed of [-{Ru₂}-POM-] inorganic linkages in (TBA)[{Ru₂(piv)₄}{Mo₆O₁₉}] ·CH₂Cl₂·C₂H₄Cl ₂ (1), (TBA)[{Ru₂(piv)₄}₂{H ₃V₁₀O₂₈}]·C₂H ₄Cl₂·7H₂O (2), and (THA)[{Ru ₂(piv)₄}₂{PMo₁₂O₄₀}] ·2(C₂H₄Cl₂) (3), respectively, where 1 is a 1-D linear chain, 2 forms a layered 2-D sheet framework, and 3 constructs a cristobalite-type 3-D structure.

Original language	English
Pages (from-to)	4852-4859
Number of pages	8
Journal	CrystEngComm
Volume	15
Issue number	24
DOIs	https://doi.org/10.1039/c3ce40426a
Publication status	Published - 2013 Jun 28

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1039/c3ce40426a

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title = "Polyoxometalate-based frameworks with a linker of paddlewheel diruthenium(ii, iii) complexes",

abstract = "The assembly reactions of a pivalate-bridged paddlewheel diruthenium(ii, iii) complex, [Ru2II,III(piv)4(THF) 2]BF4 (piv = pivalate), with three types of polyoxometalate (POM) clusters, (TBA)2[Mo6O19] (TBA = tetra-n-butylammonium cation; Lindqvist-type Mo6 POM), (TBA)3[H3V10O28] (V 10-type POM), and (THA)3[PMo12O40] (THA = tetra-n-hexylammonium cation; Keggin-type Mo12 POM), led successfully to the formation of one-, two-, and three-dimensional (1-, 2-, and 3-D) frameworks composed of [-{Ru2}-POM-] inorganic linkages in (TBA)[{Ru2(piv)4}{Mo6O19}] ·CH2Cl2·C2H4Cl 2 (1), (TBA)[{Ru2(piv)4}2{H 3V10O28}]·C2H 4Cl2·7H2O (2), and (THA)[{Ru 2(piv)4}2{PMo12O40}] ·2(C2H4Cl2) (3), respectively, where 1 is a 1-D linear chain, 2 forms a layered 2-D sheet framework, and 3 constructs a cristobalite-type 3-D structure.",

author = "Akihiro Hashikawa and Yuki Sawada and Yuma Yamamoto and Masaki Nishio and Wataru Kosaka and Yoshihito Hayashi and Hitoshi Miyasaka",

year = "2013",

month = jun,

day = "28",

doi = "10.1039/c3ce40426a",

language = "English",

volume = "15",

pages = "4852--4859",

journal = "CrystEngComm",

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publisher = "Royal Society of Chemistry",

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T1 - Polyoxometalate-based frameworks with a linker of paddlewheel diruthenium(ii, iii) complexes

AU - Hashikawa, Akihiro

AU - Sawada, Yuki

AU - Yamamoto, Yuma

AU - Nishio, Masaki

AU - Kosaka, Wataru

AU - Hayashi, Yoshihito

AU - Miyasaka, Hitoshi

PY - 2013/6/28

Y1 - 2013/6/28

N2 - The assembly reactions of a pivalate-bridged paddlewheel diruthenium(ii, iii) complex, [Ru2II,III(piv)4(THF) 2]BF4 (piv = pivalate), with three types of polyoxometalate (POM) clusters, (TBA)2[Mo6O19] (TBA = tetra-n-butylammonium cation; Lindqvist-type Mo6 POM), (TBA)3[H3V10O28] (V 10-type POM), and (THA)3[PMo12O40] (THA = tetra-n-hexylammonium cation; Keggin-type Mo12 POM), led successfully to the formation of one-, two-, and three-dimensional (1-, 2-, and 3-D) frameworks composed of [-{Ru2}-POM-] inorganic linkages in (TBA)[{Ru2(piv)4}{Mo6O19}] ·CH2Cl2·C2H4Cl 2 (1), (TBA)[{Ru2(piv)4}2{H 3V10O28}]·C2H 4Cl2·7H2O (2), and (THA)[{Ru 2(piv)4}2{PMo12O40}] ·2(C2H4Cl2) (3), respectively, where 1 is a 1-D linear chain, 2 forms a layered 2-D sheet framework, and 3 constructs a cristobalite-type 3-D structure.

AB - The assembly reactions of a pivalate-bridged paddlewheel diruthenium(ii, iii) complex, [Ru2II,III(piv)4(THF) 2]BF4 (piv = pivalate), with three types of polyoxometalate (POM) clusters, (TBA)2[Mo6O19] (TBA = tetra-n-butylammonium cation; Lindqvist-type Mo6 POM), (TBA)3[H3V10O28] (V 10-type POM), and (THA)3[PMo12O40] (THA = tetra-n-hexylammonium cation; Keggin-type Mo12 POM), led successfully to the formation of one-, two-, and three-dimensional (1-, 2-, and 3-D) frameworks composed of [-{Ru2}-POM-] inorganic linkages in (TBA)[{Ru2(piv)4}{Mo6O19}] ·CH2Cl2·C2H4Cl 2 (1), (TBA)[{Ru2(piv)4}2{H 3V10O28}]·C2H 4Cl2·7H2O (2), and (THA)[{Ru 2(piv)4}2{PMo12O40}] ·2(C2H4Cl2) (3), respectively, where 1 is a 1-D linear chain, 2 forms a layered 2-D sheet framework, and 3 constructs a cristobalite-type 3-D structure.

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DO - 10.1039/c3ce40426a

M3 - Article

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SN - 1466-8033

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EP - 4859

JO - CrystEngComm

JF - CrystEngComm

IS - 24

ER -

Polyoxometalate-based frameworks with a linker of paddlewheel diruthenium(ii, iii) complexes

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