Polyoxometalate-based frameworks with a linker of paddlewheel diruthenium(ii, iii) complexes

Akihiro Hashikawa, Yuki Sawada, Yuma Yamamoto, Masaki Nishio, Wataru Kosaka, Yoshihito Hayashi, Hitoshi Miyasaka

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)


The assembly reactions of a pivalate-bridged paddlewheel diruthenium(ii, iii) complex, [Ru2II,III(piv)4(THF) 2]BF4 (piv = pivalate), with three types of polyoxometalate (POM) clusters, (TBA)2[Mo6O19] (TBA = tetra-n-butylammonium cation; Lindqvist-type Mo6 POM), (TBA)3[H3V10O28] (V 10-type POM), and (THA)3[PMo12O40] (THA = tetra-n-hexylammonium cation; Keggin-type Mo12 POM), led successfully to the formation of one-, two-, and three-dimensional (1-, 2-, and 3-D) frameworks composed of [-{Ru2}-POM-] inorganic linkages in (TBA)[{Ru2(piv)4}{Mo6O19}] ·CH2Cl2·C2H4Cl 2 (1), (TBA)[{Ru2(piv)4}2{H 3V10O28}]·C2H 4Cl2·7H2O (2), and (THA)[{Ru 2(piv)4}2{PMo12O40}] ·2(C2H4Cl2) (3), respectively, where 1 is a 1-D linear chain, 2 forms a layered 2-D sheet framework, and 3 constructs a cristobalite-type 3-D structure.

Original languageEnglish
Pages (from-to)4852-4859
Number of pages8
Issue number24
Publication statusPublished - 2013 Jun 28

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics


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