Precipitation behavior in a Hanks' solution on Ca-P-O films prepared by laser CVD

Mitsutaka Sato; Rong Tu; Takashi Goto; Kyosuke Ueda; Takayuki Narushima

doi:10.2320/matertrans.M2009160

Precipitation behavior in a Hanks' solution on Ca-P-O films prepared by laser CVD

Mitsutaka Sato, Rong Tu, Takashi Goto, Kyosuke Ueda, Takayuki Narushima

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Ca-P-O films were prepared by laser CVD using Ca(dpm)₂ and (C₆H₅O)₃PO metal organic precursors. The crystal phase of Ca-P-O films changed depending on deposition temperature (T_dep), total pressure (P_tot), laser power (P_L) and molar ratio of Ca to P (R_Ca/p). β-TCP films in a single phase were obtained in a P-rich and high 7_dep region, while HAp films in a single phase were obtained in a Ca-rich and low T_dep region. The β-TCP films had a (220) orientation with an elongated and angular roof-shaped surface texture, whereas HAp films had a (300) orientation with a granular surface texture. Both the β-TCP film and the HAp film had a dense cross section. The Ca-P-O films were immersed in a Hanks' solution for 6 h to 7 d. Particle-shaped precipitates were observed on the β-TCP and HAp films after 3 d immersion. Needle-shaped precipitates covered the whole surface of HAp film after 7d immersion.

Original language	English
Pages (from-to)	2455-2459
Number of pages	5
Journal	Materials Transactions
Volume	50
Issue number	10
DOIs	https://doi.org/10.2320/matertrans.M2009160
Publication status	Published - 2009 Oct

Keywords

Hanks' solution
Hydroxyapatite
Laser chemical vapor deposition (CVD)
β-tricalcium phosphate

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

Access to Document

10.2320/matertrans.M2009160

Cite this

@article{a43bd62ed6ca40829b4767bb5c6daec3,

title = "Precipitation behavior in a Hanks' solution on Ca-P-O films prepared by laser CVD",

abstract = "Ca-P-O films were prepared by laser CVD using Ca(dpm)2 and (C6H5O)3PO metal organic precursors. The crystal phase of Ca-P-O films changed depending on deposition temperature (Tdep), total pressure (Ptot), laser power (PL) and molar ratio of Ca to P (RCa/p). β-TCP films in a single phase were obtained in a P-rich and high 7dep region, while HAp films in a single phase were obtained in a Ca-rich and low Tdep region. The β-TCP films had a (220) orientation with an elongated and angular roof-shaped surface texture, whereas HAp films had a (300) orientation with a granular surface texture. Both the β-TCP film and the HAp film had a dense cross section. The Ca-P-O films were immersed in a Hanks' solution for 6 h to 7 d. Particle-shaped precipitates were observed on the β-TCP and HAp films after 3 d immersion. Needle-shaped precipitates covered the whole surface of HAp film after 7d immersion.",

keywords = "Hanks' solution, Hydroxyapatite, Laser chemical vapor deposition (CVD), β-tricalcium phosphate",

author = "Mitsutaka Sato and Rong Tu and Takashi Goto and Kyosuke Ueda and Takayuki Narushima",

year = "2009",

month = oct,

doi = "10.2320/matertrans.M2009160",

language = "English",

volume = "50",

pages = "2455--2459",

journal = "Materials Transactions",

issn = "1345-9678",

publisher = "Japan Institute of Metals (JIM)",

number = "10",

}

TY - JOUR

T1 - Precipitation behavior in a Hanks' solution on Ca-P-O films prepared by laser CVD

AU - Sato, Mitsutaka

AU - Tu, Rong

AU - Goto, Takashi

AU - Ueda, Kyosuke

AU - Narushima, Takayuki

PY - 2009/10

Y1 - 2009/10

N2 - Ca-P-O films were prepared by laser CVD using Ca(dpm)2 and (C6H5O)3PO metal organic precursors. The crystal phase of Ca-P-O films changed depending on deposition temperature (Tdep), total pressure (Ptot), laser power (PL) and molar ratio of Ca to P (RCa/p). β-TCP films in a single phase were obtained in a P-rich and high 7dep region, while HAp films in a single phase were obtained in a Ca-rich and low Tdep region. The β-TCP films had a (220) orientation with an elongated and angular roof-shaped surface texture, whereas HAp films had a (300) orientation with a granular surface texture. Both the β-TCP film and the HAp film had a dense cross section. The Ca-P-O films were immersed in a Hanks' solution for 6 h to 7 d. Particle-shaped precipitates were observed on the β-TCP and HAp films after 3 d immersion. Needle-shaped precipitates covered the whole surface of HAp film after 7d immersion.

AB - Ca-P-O films were prepared by laser CVD using Ca(dpm)2 and (C6H5O)3PO metal organic precursors. The crystal phase of Ca-P-O films changed depending on deposition temperature (Tdep), total pressure (Ptot), laser power (PL) and molar ratio of Ca to P (RCa/p). β-TCP films in a single phase were obtained in a P-rich and high 7dep region, while HAp films in a single phase were obtained in a Ca-rich and low Tdep region. The β-TCP films had a (220) orientation with an elongated and angular roof-shaped surface texture, whereas HAp films had a (300) orientation with a granular surface texture. Both the β-TCP film and the HAp film had a dense cross section. The Ca-P-O films were immersed in a Hanks' solution for 6 h to 7 d. Particle-shaped precipitates were observed on the β-TCP and HAp films after 3 d immersion. Needle-shaped precipitates covered the whole surface of HAp film after 7d immersion.

KW - Hanks' solution

KW - Hydroxyapatite

KW - Laser chemical vapor deposition (CVD)

KW - β-tricalcium phosphate

UR - http://www.scopus.com/inward/record.url?scp=72149098396&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=72149098396&partnerID=8YFLogxK

U2 - 10.2320/matertrans.M2009160

DO - 10.2320/matertrans.M2009160

M3 - Article

AN - SCOPUS:72149098396

SN - 1345-9678

VL - 50

SP - 2455

EP - 2459

JO - Materials Transactions

JF - Materials Transactions

IS - 10

ER -

Precipitation behavior in a Hanks' solution on Ca-P-O films prepared by laser CVD

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this