Preparation and X‐ray crystal structure analysis of cis‐2, 4‐bis(2, 4, 6‐tri‐t‐butylphenyl)‐1, 2, 4‐oxadiphosphetane 2, 4‐disulfide and cis/trans isomerization of the corresponding 1, 2, 4‐thiadiphosphetane derivative

Kozo Toyota; Yasuhisa Ishikawa; Kotaro Shirabe; Masaaki Yoshifuji; Kengo Okada; Ken Hirotsu

doi:10.1002/hc.520040224

Preparation and X‐ray crystal structure analysis of cis‐2, 4‐bis(2, 4, 6‐tri‐t‐butylphenyl)‐1, 2, 4‐oxadiphosphetane 2, 4‐disulfide and cis/trans isomerization of the corresponding 1, 2, 4‐thiadiphosphetane derivative

Kozo Toyota, Yasuhisa Ishikawa, Kotaro Shirabe, Masaaki Yoshifuji, Kengo Okada, Ken Hirotsu

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

1,3‐Bis(2,4,6‐tri‐t‐butylphenyl)‐1,3‐diphosphaallene (1) reacted with elemental sulfur under wet reaction conditions to give cis‐ and trans‐2,4‐bis(2,4,6‐tri‐t‐butylphenyl)‐1,2,4‐thiadiphosphetane 2,4‐disulfide (cis‐2 and trans‐2) and cis‐2,4‐bis(2,4,6‐tri‐t‐butylphenyl)‐1,2,4‐oxadiphosphetane 2,4‐disulfide (cis‐3). The structure of cis‐3 was determined by X‐ray crystallography, and the cis/trans isomerization of 2 was studied.

Original language	English
Pages (from-to)	279-285
Number of pages	7
Journal	Heteroatom Chemistry
Volume	4
Issue number	2-3
DOIs	https://doi.org/10.1002/hc.520040224
Publication status	Published - 1993 Jan 1

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Chemistry(all)

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Toyota, K., Ishikawa, Y., Shirabe, K., Yoshifuji, M., Okada, K., & Hirotsu, K. (1993). Preparation and X‐ray crystal structure analysis of cis‐2, 4‐bis(2, 4, 6‐tri‐t‐butylphenyl)‐1, 2, 4‐oxadiphosphetane 2, 4‐disulfide and cis/trans isomerization of the corresponding 1, 2, 4‐thiadiphosphetane derivative. Heteroatom Chemistry, 4(2-3), 279-285. https://doi.org/10.1002/hc.520040224

Preparation and X‐ray crystal structure analysis of cis‐2, 4‐bis(2, 4, 6‐tri‐t‐butylphenyl)‐1, 2, 4‐oxadiphosphetane 2, 4‐disulfide and cis/trans isomerization of the corresponding 1, 2, 4‐thiadiphosphetane derivative. / Toyota, Kozo; Ishikawa, Yasuhisa; Shirabe, Kotaro et al.
In: Heteroatom Chemistry, Vol. 4, No. 2-3, 01.01.1993, p. 279-285.

Research output: Contribution to journal › Article › peer-review

Toyota, K, Ishikawa, Y, Shirabe, K, Yoshifuji, M, Okada, K & Hirotsu, K 1993, 'Preparation and X‐ray crystal structure analysis of cis‐2, 4‐bis(2, 4, 6‐tri‐t‐butylphenyl)‐1, 2, 4‐oxadiphosphetane 2, 4‐disulfide and cis/trans isomerization of the corresponding 1, 2, 4‐thiadiphosphetane derivative', Heteroatom Chemistry, vol. 4, no. 2-3, pp. 279-285. https://doi.org/10.1002/hc.520040224

Toyota K, Ishikawa Y, Shirabe K, Yoshifuji M, Okada K, Hirotsu K. Preparation and X‐ray crystal structure analysis of cis‐2, 4‐bis(2, 4, 6‐tri‐t‐butylphenyl)‐1, 2, 4‐oxadiphosphetane 2, 4‐disulfide and cis/trans isomerization of the corresponding 1, 2, 4‐thiadiphosphetane derivative. Heteroatom Chemistry. 1993 Jan 1;4(2-3):279-285. doi: 10.1002/hc.520040224

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title = "Preparation and X‐ray crystal structure analysis of cis‐2, 4‐bis(2, 4, 6‐tri‐t‐butylphenyl)‐1, 2, 4‐oxadiphosphetane 2, 4‐disulfide and cis/trans isomerization of the corresponding 1, 2, 4‐thiadiphosphetane derivative",

abstract = "1,3‐Bis(2,4,6‐tri‐t‐butylphenyl)‐1,3‐diphosphaallene (1) reacted with elemental sulfur under wet reaction conditions to give cis‐ and trans‐2,4‐bis(2,4,6‐tri‐t‐butylphenyl)‐1,2,4‐thiadiphosphetane 2,4‐disulfide (cis‐2 and trans‐2) and cis‐2,4‐bis(2,4,6‐tri‐t‐butylphenyl)‐1,2,4‐oxadiphosphetane 2,4‐disulfide (cis‐3). The structure of cis‐3 was determined by X‐ray crystallography, and the cis/trans isomerization of 2 was studied.",

author = "Kozo Toyota and Yasuhisa Ishikawa and Kotaro Shirabe and Masaaki Yoshifuji and Kengo Okada and Ken Hirotsu",

year = "1993",

month = jan,

day = "1",

doi = "10.1002/hc.520040224",

language = "English",

volume = "4",

pages = "279--285",

journal = "Heteroatom Chemistry",

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publisher = "Wiley-Blackwell",

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T1 - Preparation and X‐ray crystal structure analysis of cis‐2, 4‐bis(2, 4, 6‐tri‐t‐butylphenyl)‐1, 2, 4‐oxadiphosphetane 2, 4‐disulfide and cis/trans isomerization of the corresponding 1, 2, 4‐thiadiphosphetane derivative

AU - Toyota, Kozo

AU - Ishikawa, Yasuhisa

AU - Shirabe, Kotaro

AU - Yoshifuji, Masaaki

AU - Okada, Kengo

AU - Hirotsu, Ken

PY - 1993/1/1

Y1 - 1993/1/1

N2 - 1,3‐Bis(2,4,6‐tri‐t‐butylphenyl)‐1,3‐diphosphaallene (1) reacted with elemental sulfur under wet reaction conditions to give cis‐ and trans‐2,4‐bis(2,4,6‐tri‐t‐butylphenyl)‐1,2,4‐thiadiphosphetane 2,4‐disulfide (cis‐2 and trans‐2) and cis‐2,4‐bis(2,4,6‐tri‐t‐butylphenyl)‐1,2,4‐oxadiphosphetane 2,4‐disulfide (cis‐3). The structure of cis‐3 was determined by X‐ray crystallography, and the cis/trans isomerization of 2 was studied.

AB - 1,3‐Bis(2,4,6‐tri‐t‐butylphenyl)‐1,3‐diphosphaallene (1) reacted with elemental sulfur under wet reaction conditions to give cis‐ and trans‐2,4‐bis(2,4,6‐tri‐t‐butylphenyl)‐1,2,4‐thiadiphosphetane 2,4‐disulfide (cis‐2 and trans‐2) and cis‐2,4‐bis(2,4,6‐tri‐t‐butylphenyl)‐1,2,4‐oxadiphosphetane 2,4‐disulfide (cis‐3). The structure of cis‐3 was determined by X‐ray crystallography, and the cis/trans isomerization of 2 was studied.

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Preparation and X‐ray crystal structure analysis of cis‐2, 4‐bis(2, 4, 6‐tri‐t‐butylphenyl)‐1, 2, 4‐oxadiphosphetane 2, 4‐disulfide and cis/trans isomerization of the corresponding 1, 2, 4‐thiadiphosphetane derivative

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