Preparation of alginate-polymethacrylate hybrid material by radical polymerization of cationic methacrylate monomer in the presence of sodium alginate

Jun Ichi Kadokawa; Shingo Saitou; Shin Ichiro Shoda

doi:10.1016/j.carbpol.2005.01.006

Preparation of alginate-polymethacrylate hybrid material by radical polymerization of cationic methacrylate monomer in the presence of sodium alginate

Jun Ichi Kadokawa, Shingo Saitou, Shin Ichiro Shoda

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

An alginate-polymethacrylate hybrid material was prepared by radical polymerization of a cationic methacrylate monomer, i.e. 2-aminoethyl methacrylate hydrochloride in the presence of sodium alginate in water. The insoluble material was formed with progress of the polymerization. The structure of the product was confirmed by the IR spectrum and elemental analysis, as well as the acid hydrolysis experiment to be composed of alginate and polymethacrylate. The TG and DSC data of product were different from those of a mixture of sodium alginate with poly(2-aminoethyl methacrylate hydrochloride). Furthermore, the films of the hybrid materials could be formed by means of the polymerization of the methacrylate monomer in the presence of sodium alginate, followed by the evaporation of the solvent.

Original language	English
Pages (from-to)	253-258
Number of pages	6
Journal	Carbohydrate Polymers
Volume	60
Issue number	2
DOIs	https://doi.org/10.1016/j.carbpol.2005.01.006
Publication status	Published - 2005 May 6
Externally published	Yes

Keywords

Alginate
Hybrid material
Polymerization
Polysaccharide

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Materials Chemistry

Access to Document

10.1016/j.carbpol.2005.01.006

Cite this

@article{857065362d89464cb618b464a1bb4f73,

title = "Preparation of alginate-polymethacrylate hybrid material by radical polymerization of cationic methacrylate monomer in the presence of sodium alginate",

abstract = "An alginate-polymethacrylate hybrid material was prepared by radical polymerization of a cationic methacrylate monomer, i.e. 2-aminoethyl methacrylate hydrochloride in the presence of sodium alginate in water. The insoluble material was formed with progress of the polymerization. The structure of the product was confirmed by the IR spectrum and elemental analysis, as well as the acid hydrolysis experiment to be composed of alginate and polymethacrylate. The TG and DSC data of product were different from those of a mixture of sodium alginate with poly(2-aminoethyl methacrylate hydrochloride). Furthermore, the films of the hybrid materials could be formed by means of the polymerization of the methacrylate monomer in the presence of sodium alginate, followed by the evaporation of the solvent.",

keywords = "Alginate, Hybrid material, Polymerization, Polysaccharide",

author = "Kadokawa, {Jun Ichi} and Shingo Saitou and Shoda, {Shin Ichiro}",

note = "Funding Information: J.K. acknowledges a Grant-in-Aid for Scientific Research from Ministry of Education, Culture, Sports, Science, and Technology, Japan (No. 14550830).",

year = "2005",

month = may,

day = "6",

doi = "10.1016/j.carbpol.2005.01.006",

language = "English",

volume = "60",

pages = "253--258",

journal = "Carbohydrate Polymers",

issn = "0144-8617",

publisher = "Elsevier Limited",

number = "2",

}

TY - JOUR

T1 - Preparation of alginate-polymethacrylate hybrid material by radical polymerization of cationic methacrylate monomer in the presence of sodium alginate

AU - Kadokawa, Jun Ichi

AU - Saitou, Shingo

AU - Shoda, Shin Ichiro

N1 - Funding Information: J.K. acknowledges a Grant-in-Aid for Scientific Research from Ministry of Education, Culture, Sports, Science, and Technology, Japan (No. 14550830).

PY - 2005/5/6

Y1 - 2005/5/6

N2 - An alginate-polymethacrylate hybrid material was prepared by radical polymerization of a cationic methacrylate monomer, i.e. 2-aminoethyl methacrylate hydrochloride in the presence of sodium alginate in water. The insoluble material was formed with progress of the polymerization. The structure of the product was confirmed by the IR spectrum and elemental analysis, as well as the acid hydrolysis experiment to be composed of alginate and polymethacrylate. The TG and DSC data of product were different from those of a mixture of sodium alginate with poly(2-aminoethyl methacrylate hydrochloride). Furthermore, the films of the hybrid materials could be formed by means of the polymerization of the methacrylate monomer in the presence of sodium alginate, followed by the evaporation of the solvent.

AB - An alginate-polymethacrylate hybrid material was prepared by radical polymerization of a cationic methacrylate monomer, i.e. 2-aminoethyl methacrylate hydrochloride in the presence of sodium alginate in water. The insoluble material was formed with progress of the polymerization. The structure of the product was confirmed by the IR spectrum and elemental analysis, as well as the acid hydrolysis experiment to be composed of alginate and polymethacrylate. The TG and DSC data of product were different from those of a mixture of sodium alginate with poly(2-aminoethyl methacrylate hydrochloride). Furthermore, the films of the hybrid materials could be formed by means of the polymerization of the methacrylate monomer in the presence of sodium alginate, followed by the evaporation of the solvent.

KW - Alginate

KW - Hybrid material

KW - Polymerization

KW - Polysaccharide

UR - http://www.scopus.com/inward/record.url?scp=16644382049&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=16644382049&partnerID=8YFLogxK

U2 - 10.1016/j.carbpol.2005.01.006

DO - 10.1016/j.carbpol.2005.01.006

M3 - Article

AN - SCOPUS:16644382049

SN - 0144-8617

VL - 60

SP - 253

EP - 258

JO - Carbohydrate Polymers

JF - Carbohydrate Polymers

IS - 2

ER -

Preparation of alginate-polymethacrylate hybrid material by radical polymerization of cationic methacrylate monomer in the presence of sodium alginate

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this