The honeycomb-structured film has advantages such as high wettability and high surface area. This structure and properties are suitable for the capacitor electrode. In this study, the electrode structure is controlled by the synthesis of MnO 2 nanoparticles using the breath figure method. The electrode performance was calculated by electrochemical measurements. As a result, the capacitance value was 100.5 F/g at 1 mV s -1 , which was improved 2.7 times as compared with that without structure control.