TY - GEN
T1 - Preparation of titanium subchloride and its electrodeposit in chloride melts
AU - Wang, Qiuyu
AU - Du, Chao
AU - Liu, Yong
AU - Jiao, Shuqiang
AU - Zhu, Hongmin
PY - 2012
Y1 - 2012
N2 - This work proposed a process to prepare titanium subchlorides by using titanium and titanium tetrachloride as raw materials in an equimolar ratio of KCl-NaCl melt. According to the reactions Ti4++Ti 2Ti2+, Ti4+ +Ti2+ 2Ti3+, different molar ratio of Ti2+/Ti3+ titanium subchlordie salts could be prepared by controlling the ratio of raw materials. And the concentration of Ti2+ can be measured by the molar mass of hydrogen based on the reaction, Ti 2+ +H+ ⇌ Ti3+ +1/2H2. The total titanium chloride concentration was measured by the Diantipyryl Methane Photometric method. The prepared titanium subchloride was used as electro-activation ions for the titanium deposits in KCl-NaCl melts at 720° C.
AB - This work proposed a process to prepare titanium subchlorides by using titanium and titanium tetrachloride as raw materials in an equimolar ratio of KCl-NaCl melt. According to the reactions Ti4++Ti 2Ti2+, Ti4+ +Ti2+ 2Ti3+, different molar ratio of Ti2+/Ti3+ titanium subchlordie salts could be prepared by controlling the ratio of raw materials. And the concentration of Ti2+ can be measured by the molar mass of hydrogen based on the reaction, Ti 2+ +H+ ⇌ Ti3+ +1/2H2. The total titanium chloride concentration was measured by the Diantipyryl Methane Photometric method. The prepared titanium subchloride was used as electro-activation ions for the titanium deposits in KCl-NaCl melts at 720° C.
KW - Disproportionate reactions
KW - KCl-NaCl
KW - Ti/Ti concentration ratio
KW - Titanium subchlorides
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UR - http://www.scopus.com/inward/citedby.url?scp=84883091653&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:84883091653
SN - 9787030338990
T3 - Ti 2011 - Proceedings of the 12th World Conference on Titanium
SP - 177
EP - 180
BT - Ti 2011 - Proceedings of the 12th World Conference on Titanium
T2 - 12th World Conference on Titanium, Ti 2011
Y2 - 19 June 2011 through 24 June 2011
ER -