Pressure effect on the three-dimensional charge-transfer ferromagnet [{Ru2(m-FPhCO2)4}2(BTDA-TCNQ)]

Natsuko Motokawa; Hitoshi Miyasaka; Masahiro Yamashita

doi:10.1039/b925685g

Pressure effect on the three-dimensional charge-transfer ferromagnet [{Ru₂(m-FPhCO₂)₄}₂(BTDA-TCNQ)]

Natsuko Motokawa, Hitoshi Miyasaka, Masahiro Yamashita

IMR - Materials Development Division

Tohoku University

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The magnetic properties of a three-dimensional infinite network compound, [{Ru₂(m-FPhCO₂)₄}₂(BTDA-TCNQ)] (m-FPhCO₂^- = m-fluorobenzoate; BTDA-TCNQ = bis(1,2,5-thiadiazolo)tetracyanoquinodimethane), were investigated under hydrostatic pressures up to 12.9 kbar. The applied pressure caused the intralattice exchange couplings to weaken, inducing a decrease in the magnetic phase transition temperature from 107 K at ambient pressure to 57 K at 12.9 kbar.

Original language	English
Pages (from-to)	4724-4726
Number of pages	3
Journal	Dalton Transactions
Volume	39
Issue number	20
DOIs	https://doi.org/10.1039/b925685g
Publication status	Published - 2010

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abstract = "The magnetic properties of a three-dimensional infinite network compound, [{Ru2(m-FPhCO2)4}2(BTDA-TCNQ)] (m-FPhCO2- = m-fluorobenzoate; BTDA-TCNQ = bis(1,2,5-thiadiazolo)tetracyanoquinodimethane), were investigated under hydrostatic pressures up to 12.9 kbar. The applied pressure caused the intralattice exchange couplings to weaken, inducing a decrease in the magnetic phase transition temperature from 107 K at ambient pressure to 57 K at 12.9 kbar.",

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AU - Miyasaka, Hitoshi

AU - Yamashita, Masahiro

PY - 2010

Y1 - 2010

N2 - The magnetic properties of a three-dimensional infinite network compound, [{Ru2(m-FPhCO2)4}2(BTDA-TCNQ)] (m-FPhCO2- = m-fluorobenzoate; BTDA-TCNQ = bis(1,2,5-thiadiazolo)tetracyanoquinodimethane), were investigated under hydrostatic pressures up to 12.9 kbar. The applied pressure caused the intralattice exchange couplings to weaken, inducing a decrease in the magnetic phase transition temperature from 107 K at ambient pressure to 57 K at 12.9 kbar.

AB - The magnetic properties of a three-dimensional infinite network compound, [{Ru2(m-FPhCO2)4}2(BTDA-TCNQ)] (m-FPhCO2- = m-fluorobenzoate; BTDA-TCNQ = bis(1,2,5-thiadiazolo)tetracyanoquinodimethane), were investigated under hydrostatic pressures up to 12.9 kbar. The applied pressure caused the intralattice exchange couplings to weaken, inducing a decrease in the magnetic phase transition temperature from 107 K at ambient pressure to 57 K at 12.9 kbar.

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Pressure effect on the three-dimensional charge-transfer ferromagnet [{Ru₂(m-FPhCO₂)₄}₂(BTDA-TCNQ)]

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