TY - JOUR
T1 - Pretreatment combining ultrasound and sodium percarbonate under mild conditions for efficient degradation of corn stover
AU - Nakashima, Kazunori
AU - Ebi, Yuuki
AU - Kubo, Masaki
AU - Shibasaki-Kitakawa, Naomi
AU - Yonemoto, Toshikuni
N1 - Funding Information:
This work was partly supported by the Japan Society for the Promotion of Science KAKENHI (Grant Number: 25820396 ) and JST A-STEP program ( 241FT0189 ). We would like to thank Professors Tomohito Kameda and Toshiaki Yoshioka (Tohoku University) for their technical help on XRD system.
Publisher Copyright:
© 2015 Elsevier B.V.
PY - 2016/3/1
Y1 - 2016/3/1
N2 - Ultrasound (US) can be used to disrupt microcrystalline cellulose to give nanofibers via ultrasonic cavitation. Sodium percarbonate (SP), consisting of sodium carbonate and hydrogen peroxide, generates highly reactive radicals, which cause oxidative delignification. Here, we describe a novel pretreatment technique using a combination of US and SP (US-SP) for the efficient saccharification of cellulose and hemicellulose in lignocellulosic corn stover. Although US-SP pretreatment was conducted under mild condition (i.e., at room temperature and atmospheric pressure), the pretreatment greatly increased lignin removal and cellulose digestibility. We also determined the optimum US-SP treatment conditions, such as ultrasonic power output, pretreatment time, pretreatment temperature, and SP concentration for an efficient cellulose saccharification. Moreover, xylose could be effectively recovered from US-SP pretreated biomass without the formation of microbial inhibitor furfural.
AB - Ultrasound (US) can be used to disrupt microcrystalline cellulose to give nanofibers via ultrasonic cavitation. Sodium percarbonate (SP), consisting of sodium carbonate and hydrogen peroxide, generates highly reactive radicals, which cause oxidative delignification. Here, we describe a novel pretreatment technique using a combination of US and SP (US-SP) for the efficient saccharification of cellulose and hemicellulose in lignocellulosic corn stover. Although US-SP pretreatment was conducted under mild condition (i.e., at room temperature and atmospheric pressure), the pretreatment greatly increased lignin removal and cellulose digestibility. We also determined the optimum US-SP treatment conditions, such as ultrasonic power output, pretreatment time, pretreatment temperature, and SP concentration for an efficient cellulose saccharification. Moreover, xylose could be effectively recovered from US-SP pretreated biomass without the formation of microbial inhibitor furfural.
KW - Cellulose
KW - Enzymatic saccharification
KW - Lignocellulose
KW - Pretreatment
KW - Ultrasound
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U2 - 10.1016/j.ultsonch.2015.10.017
DO - 10.1016/j.ultsonch.2015.10.017
M3 - Article
C2 - 26547502
AN - SCOPUS:84947257930
SN - 1350-4177
VL - 29
SP - 455
EP - 460
JO - Ultrasonics Sonochemistry
JF - Ultrasonics Sonochemistry
ER -