Production of acetic acid from carbohydrate biomass by two-step reaction with alkaline hydrothermal reaction and wet oxidation

X. Yan, Fangming Jin, Kazuyuki Tohji, H. Enomoto

Research output: Chapter in Book/Report/Conference proceedingConference contribution

5 Citations (Scopus)

Abstract

An investigation was carried out to improve the production of acetic acid by an alkaline two-step process, in which the first step is to accelerate the formation of lactic acid in a hydrothermal reaction with the addition of alkali, and the second step is further convert the lactic acid produced in the first step to acetic acid by oxidation with newly added oxygen. Results showed that the addition of alkali promoted selectively the formation of lactic acid from glucose at a hydrothermal condition. Acetic acid yield in the alkaline two-step process greatly increased in comparison to that without the addition of any alkali. In the alkaline two-step process, the highest acetic acid yield arrived at 27 % on the carbon base under the conditions of reaction temperature of 300 °C, reaction time of 1 min, and Ca(OH)2 concentration of 0.32 M in the first step, and reaction temperature of 300 °C, reaction time of 3 min, and oxygen supply of 70 % in the second step.

Original languageEnglish
Title of host publicationWATER DYANMICS
Subtitle of host publication4th International Workshop on Water Dynamics
Pages182-185
Number of pages4
DOIs
Publication statusPublished - 2007 May 11
Event4th International Workshop on Water Dynamics - Sendai, Japan
Duration: 2006 Nov 72006 Nov 8

Publication series

NameAIP Conference Proceedings
Volume898
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Other

Other4th International Workshop on Water Dynamics
Country/TerritoryJapan
CitySendai
Period06/11/706/11/8

Keywords

  • Acetic acid
  • Alkaline
  • Carbohydrates
  • Hydrothermal reaction
  • Lactic acid

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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