Properties of selected sulfonated polymers as proton-conducting electrolytes for polymer electrolyte fuel cells

J. M. Bae; I. Honma; M. Murata; T. Yamamoto; M. Rikukawa; N. Ogata

doi:10.1016/S0167-2738(02)00011-5

Properties of selected sulfonated polymers as proton-conducting electrolytes for polymer electrolyte fuel cells

J. M. Bae, I. Honma, M. Murata, T. Yamamoto, M. Rikukawa, N. Ogata

IMRAM - Center for Mineral Processing and Metallurgy (CMPM)

Research output: Contribution to journal › Article › peer-review

202 Citations (Scopus)

Abstract

Two kinds of polymers were fabricated and tested as candidates of proton-conducting membranes for polymer electrolyte fuel cell (PEFC) applications. Poly benzimidazole (PBI) and poly(4-phenoxybenzoyl-1,4-phenylene, Poly-X 2000) (PPBP) were sulfonated and characterized as proton-conducting membranes. PBI was sulfonated as PBI-PS (propanesultone) and PBI-BS (butanesultone). PPBP was prepared at various sulfonation levels. Proton conductivities were measured at 60-160 °C. Power output characteristics of both polymers were measured by using commercial Pt/C electrodes.

Original language	English
Pages (from-to)	189-194
Number of pages	6
Journal	Solid State Ionics
Volume	147
Issue number	1-2
DOIs	https://doi.org/10.1016/S0167-2738(02)00011-5
Publication status	Published - 2002 Mar 1

Keywords

Carbon monoxide intoxication
Fuel cell
PBI
PBI-BS
PBI-PS
PEFC
PEMFC
Poly(4-phenoxybenzoyl-1,4-phenylene)
Polybenzimidazole
PPBP
Proton conductivity
Proton exchange membrane
S-PPBP
Solid polymer electrolyte
Sulfonation

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title = "Properties of selected sulfonated polymers as proton-conducting electrolytes for polymer electrolyte fuel cells",

abstract = "Two kinds of polymers were fabricated and tested as candidates of proton-conducting membranes for polymer electrolyte fuel cell (PEFC) applications. Poly benzimidazole (PBI) and poly(4-phenoxybenzoyl-1,4-phenylene, Poly-X 2000) (PPBP) were sulfonated and characterized as proton-conducting membranes. PBI was sulfonated as PBI-PS (propanesultone) and PBI-BS (butanesultone). PPBP was prepared at various sulfonation levels. Proton conductivities were measured at 60-160 °C. Power output characteristics of both polymers were measured by using commercial Pt/C electrodes.",

keywords = "Carbon monoxide intoxication, Fuel cell, PBI, PBI-BS, PBI-PS, PEFC, PEMFC, Poly(4-phenoxybenzoyl-1,4-phenylene), Polybenzimidazole, PPBP, Proton conductivity, Proton exchange membrane, S-PPBP, Solid polymer electrolyte, Sulfonation",

author = "Bae, {J. M.} and I. Honma and M. Murata and T. Yamamoto and M. Rikukawa and N. Ogata",

note = "Funding Information: This work was supported by the Proposal-based Advanced Industrial Technology R and D Program from the New Energy and Industrial Technology Development Organization (NEDO), Japan.",

year = "2002",

month = mar,

day = "1",

doi = "10.1016/S0167-2738(02)00011-5",

language = "English",

volume = "147",

pages = "189--194",

journal = "Solid State Ionics",

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number = "1-2",

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TY - JOUR

T1 - Properties of selected sulfonated polymers as proton-conducting electrolytes for polymer electrolyte fuel cells

AU - Bae, J. M.

AU - Honma, I.

AU - Murata, M.

AU - Yamamoto, T.

AU - Rikukawa, M.

AU - Ogata, N.

N1 - Funding Information: This work was supported by the Proposal-based Advanced Industrial Technology R and D Program from the New Energy and Industrial Technology Development Organization (NEDO), Japan.

PY - 2002/3/1

Y1 - 2002/3/1

N2 - Two kinds of polymers were fabricated and tested as candidates of proton-conducting membranes for polymer electrolyte fuel cell (PEFC) applications. Poly benzimidazole (PBI) and poly(4-phenoxybenzoyl-1,4-phenylene, Poly-X 2000) (PPBP) were sulfonated and characterized as proton-conducting membranes. PBI was sulfonated as PBI-PS (propanesultone) and PBI-BS (butanesultone). PPBP was prepared at various sulfonation levels. Proton conductivities were measured at 60-160 °C. Power output characteristics of both polymers were measured by using commercial Pt/C electrodes.

AB - Two kinds of polymers were fabricated and tested as candidates of proton-conducting membranes for polymer electrolyte fuel cell (PEFC) applications. Poly benzimidazole (PBI) and poly(4-phenoxybenzoyl-1,4-phenylene, Poly-X 2000) (PPBP) were sulfonated and characterized as proton-conducting membranes. PBI was sulfonated as PBI-PS (propanesultone) and PBI-BS (butanesultone). PPBP was prepared at various sulfonation levels. Proton conductivities were measured at 60-160 °C. Power output characteristics of both polymers were measured by using commercial Pt/C electrodes.

KW - Carbon monoxide intoxication

KW - Fuel cell

KW - PBI

KW - PBI-BS

KW - PBI-PS

KW - PEFC

KW - PEMFC

KW - Poly(4-phenoxybenzoyl-1,4-phenylene)

KW - Polybenzimidazole

KW - PPBP

KW - Proton conductivity

KW - Proton exchange membrane

KW - S-PPBP

KW - Solid polymer electrolyte

KW - Sulfonation

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U2 - 10.1016/S0167-2738(02)00011-5

DO - 10.1016/S0167-2738(02)00011-5

M3 - Article

AN - SCOPUS:0036499347

SN - 0167-2738

VL - 147

SP - 189

EP - 194

JO - Solid State Ionics

JF - Solid State Ionics

IS - 1-2

ER -

Properties of selected sulfonated polymers as proton-conducting electrolytes for polymer electrolyte fuel cells

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Keywords

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