Reaction of dichlorocarbene with 1‐(2,4,6‐tri‐t‐butylphenyl)‐1‐phosphaallenes

Masaaki Yoshifuji, Manabu Shibata, Kozo Toyota, Ikuko Miyahara, Ken Hirotsu

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)


1‐(2,4,6‐Tri‐t‐butylphenyl)‐1‐phosphaallene reacted with dichlorocarbene to give 2‐dichloromethylene‐1‐(2,4,6‐tri‐t‐butylphenyl)‐1‐phosphirane. The structure was confirmed by X‐ray crystal structure analysis. A similar isomerization product was obtained in the reaction of dichlorocarbene with 3‐phenyl‐1‐(2,4,6‐tri‐t‐butylphenyl)‐1‐phosphaallene.

Original languageEnglish
Pages (from-to)195-200
Number of pages6
JournalHeteroatom Chemistry
Issue number3
Publication statusPublished - 1994 Jun


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