TY - JOUR
T1 - Reaction of dichlorocarbene with 1‐(2,4,6‐tri‐t‐butylphenyl)‐1‐phosphaallenes
AU - Yoshifuji, Masaaki
AU - Shibata, Manabu
AU - Toyota, Kozo
AU - Miyahara, Ikuko
AU - Hirotsu, Ken
PY - 1994/6
Y1 - 1994/6
N2 - 1‐(2,4,6‐Tri‐t‐butylphenyl)‐1‐phosphaallene reacted with dichlorocarbene to give 2‐dichloromethylene‐1‐(2,4,6‐tri‐t‐butylphenyl)‐1‐phosphirane. The structure was confirmed by X‐ray crystal structure analysis. A similar isomerization product was obtained in the reaction of dichlorocarbene with 3‐phenyl‐1‐(2,4,6‐tri‐t‐butylphenyl)‐1‐phosphaallene.
AB - 1‐(2,4,6‐Tri‐t‐butylphenyl)‐1‐phosphaallene reacted with dichlorocarbene to give 2‐dichloromethylene‐1‐(2,4,6‐tri‐t‐butylphenyl)‐1‐phosphirane. The structure was confirmed by X‐ray crystal structure analysis. A similar isomerization product was obtained in the reaction of dichlorocarbene with 3‐phenyl‐1‐(2,4,6‐tri‐t‐butylphenyl)‐1‐phosphaallene.
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U2 - 10.1002/hc.520050302
DO - 10.1002/hc.520050302
M3 - Article
AN - SCOPUS:84987589816
SN - 1042-7163
VL - 5
SP - 195
EP - 200
JO - Heteroatom Chemistry
JF - Heteroatom Chemistry
IS - 3
ER -