Reaction of silyl(carbonyl)iron complexes with liAlH4 giving methylsilanes: Reduction of a carbonyl ligand and coupling with a silyl group

Hiromi Tobita; Rie Shiozawa; Hiroshi Ogino

doi:10.1246/cl.1997.805

Reaction of silyl(carbonyl)iron complexes with liAlH₄ giving methylsilanes: Reduction of a carbonyl ligand and coupling with a silyl group

Hiromi Tobita, Rie Shiozawa, Hiroshi Ogino

IEHE - Institute for Excellence in Higher Education (organization affiliation only)

Tohoku University

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Treatment of CpFe(CO)₂SiR₃ (R₃ = (^pTol)₂H, (^pTol)₂Me, MePh(1-Nap); 1-Nap = 1-naphthyl) with LiAlH₄ in ether or THF at room temperature gave CH₃SiR₃ as a major product in moderate to high yield. The labeling experiments using LiAlD₄ and C_pFe(¹³CO)₂SiR(^pTol)₂ (R = H, Me) proved unambiguously that the carbonyl ligand is reduced with LiAlH₄ and coupled with the silyl group to give the methylsilanc.

Original language	English
Pages (from-to)	805-806
Number of pages	2
Journal	Chemistry Letters
Issue number	8
DOIs	https://doi.org/10.1246/cl.1997.805
Publication status	Published - 1997

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10.1246/cl.1997.805

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title = "Reaction of silyl(carbonyl)iron complexes with liAlH4 giving methylsilanes: Reduction of a carbonyl ligand and coupling with a silyl group",

abstract = "Treatment of CpFe(CO)2SiR3 (R3 = (pTol)2H, (pTol)2Me, MePh(1-Nap); 1-Nap = 1-naphthyl) with LiAlH4 in ether or THF at room temperature gave CH3SiR3 as a major product in moderate to high yield. The labeling experiments using LiAlD4 and CpFe(13CO)2SiR(pTol)2 (R = H, Me) proved unambiguously that the carbonyl ligand is reduced with LiAlH4 and coupled with the silyl group to give the methylsilanc.",

author = "Hiromi Tobita and Rie Shiozawa and Hiroshi Ogino",

year = "1997",

doi = "10.1246/cl.1997.805",

language = "English",

pages = "805--806",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

number = "8",

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TY - JOUR

T1 - Reaction of silyl(carbonyl)iron complexes with liAlH4 giving methylsilanes

T2 - Reduction of a carbonyl ligand and coupling with a silyl group

AU - Tobita, Hiromi

AU - Shiozawa, Rie

AU - Ogino, Hiroshi

PY - 1997

Y1 - 1997

N2 - Treatment of CpFe(CO)2SiR3 (R3 = (pTol)2H, (pTol)2Me, MePh(1-Nap); 1-Nap = 1-naphthyl) with LiAlH4 in ether or THF at room temperature gave CH3SiR3 as a major product in moderate to high yield. The labeling experiments using LiAlD4 and CpFe(13CO)2SiR(pTol)2 (R = H, Me) proved unambiguously that the carbonyl ligand is reduced with LiAlH4 and coupled with the silyl group to give the methylsilanc.

AB - Treatment of CpFe(CO)2SiR3 (R3 = (pTol)2H, (pTol)2Me, MePh(1-Nap); 1-Nap = 1-naphthyl) with LiAlH4 in ether or THF at room temperature gave CH3SiR3 as a major product in moderate to high yield. The labeling experiments using LiAlD4 and CpFe(13CO)2SiR(pTol)2 (R = H, Me) proved unambiguously that the carbonyl ligand is reduced with LiAlH4 and coupled with the silyl group to give the methylsilanc.

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DO - 10.1246/cl.1997.805

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SN - 0366-7022

SP - 805

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 8

ER -

Reaction of silyl(carbonyl)iron complexes with liAlH₄ giving methylsilanes: Reduction of a carbonyl ligand and coupling with a silyl group

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