TY - JOUR
T1 - Reactivity of hydrogen and ternary nitrides containing lithium and 13 group elements
AU - Yamane, Hisanori
AU - Kano, Tomomi
AU - Kamegawa, Atsunori
AU - Shibata, Masatoshi
AU - Yamada, Takahiro
AU - Okada, Masuo
AU - Shimada, Masahiko
N1 - Funding Information:
This work was partially supported by The Collaborative Research in Center for Interdisciplinary Research, Tohoku University.
PY - 2005/10/27
Y1 - 2005/10/27
N2 - Ternary nitrides, Li3XN2 (X = B, Al, Ga), were prepared at 973-1073 K in N2 by solid state reaction of Li 3N and XN. Among these three compounds, Li3GaN2 reacted with H2 gas at 573 K and changed into a mixture of LiNH 2, LiH, and GaN. The amount of hydrogen reacted was 3.4 mass% to the amount of Li3GaN2, and 1.7 mass% of hydrogen was released under a reduced pressure.
AB - Ternary nitrides, Li3XN2 (X = B, Al, Ga), were prepared at 973-1073 K in N2 by solid state reaction of Li 3N and XN. Among these three compounds, Li3GaN2 reacted with H2 gas at 573 K and changed into a mixture of LiNH 2, LiH, and GaN. The amount of hydrogen reacted was 3.4 mass% to the amount of Li3GaN2, and 1.7 mass% of hydrogen was released under a reduced pressure.
KW - Chemical synthesis
KW - Hydrogen storage materials
KW - Pressure-composition isotherm
KW - X-ray diffraction
UR - http://www.scopus.com/inward/record.url?scp=25844490111&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=25844490111&partnerID=8YFLogxK
U2 - 10.1016/j.jallcom.2005.01.064
DO - 10.1016/j.jallcom.2005.01.064
M3 - Letter
AN - SCOPUS:25844490111
SN - 0925-8388
VL - 402
SP - L1-L3
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
IS - 1-2
ER -