TY - JOUR
T1 - Recombination of an Fe-Si-P linkage to an Fe-P-Si linkage through an isolable intermediate phosphasilaferracyclopropane
AU - Okazaki, Masaaki
AU - Yoshitomi, Takahiko
AU - Naito, Junpei
AU - Sato, Akira
AU - Komuro, Takashi
AU - Tobita, Hiromi
PY - 2008/12/31
Y1 - 2008/12/31
N2 - Phosphasilaferracycle [Cp*(CO)Fe{κ2Si,P-SiMe 2PPh2}], prepared upon irradiation of [Cp*(CO) 2FeSiMe2PPh2], was converted to [Cp*(CO)2FeP(Ph)SiMe2Ph] under mild conditions. The unusual recombination of the iron, silicon, and phosphorus cores could be achieved through a sequence of 1,2- and 1,3-group migrations in an FeSiP system.
AB - Phosphasilaferracycle [Cp*(CO)Fe{κ2Si,P-SiMe 2PPh2}], prepared upon irradiation of [Cp*(CO) 2FeSiMe2PPh2], was converted to [Cp*(CO)2FeP(Ph)SiMe2Ph] under mild conditions. The unusual recombination of the iron, silicon, and phosphorus cores could be achieved through a sequence of 1,2- and 1,3-group migrations in an FeSiP system.
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U2 - 10.1021/ja808443v
DO - 10.1021/ja808443v
M3 - Short survey
AN - SCOPUS:67849101945
SN - 0002-7863
VL - 130
SP - 17674
EP - 17675
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 52
ER -