Regioselective [2 + 2]-photocycloaddition reactions of chiral tetronates - Influence of temperature, pressure, and reaction medium

Martin Fleck; Cheng Yang; Takehiko Wada; Yoshihisa Inoue; Thorsten Bach

doi:10.1039/b613985j

Regioselective [2 + 2]-photocycloaddition reactions of chiral tetronates - Influence of temperature, pressure, and reaction medium

Martin Fleck, Cheng Yang, Takehiko Wada, Yoshihisa Inoue, Thorsten Bach

IMRAM - Division of Organic- and Biomaterials Research

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

The intramolecular [2 + 2]-photocycloaddition of the 1,3-divinyl-2- cyclopentyl tetronates 1 was performed under various conditions to give perfect diastereoselectivity and a regioselectivity of up to 85/15 in the presence of γ-cyclodextrin by differentiating the two chemically very similar double bonds of 1.

Original language	English
Pages (from-to)	822-824
Number of pages	3
Journal	Chemical Communications
Issue number	8
DOIs	https://doi.org/10.1039/b613985j
Publication status	Published - 2007

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abstract = "The intramolecular [2 + 2]-photocycloaddition of the 1,3-divinyl-2- cyclopentyl tetronates 1 was performed under various conditions to give perfect diastereoselectivity and a regioselectivity of up to 85/15 in the presence of γ-cyclodextrin by differentiating the two chemically very similar double bonds of 1.",

author = "Martin Fleck and Cheng Yang and Takehiko Wada and Yoshihisa Inoue and Thorsten Bach",

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T1 - Regioselective [2 + 2]-photocycloaddition reactions of chiral tetronates - Influence of temperature, pressure, and reaction medium

AU - Fleck, Martin

AU - Yang, Cheng

AU - Wada, Takehiko

AU - Inoue, Yoshihisa

AU - Bach, Thorsten

PY - 2007

Y1 - 2007

N2 - The intramolecular [2 + 2]-photocycloaddition of the 1,3-divinyl-2- cyclopentyl tetronates 1 was performed under various conditions to give perfect diastereoselectivity and a regioselectivity of up to 85/15 in the presence of γ-cyclodextrin by differentiating the two chemically very similar double bonds of 1.

AB - The intramolecular [2 + 2]-photocycloaddition of the 1,3-divinyl-2- cyclopentyl tetronates 1 was performed under various conditions to give perfect diastereoselectivity and a regioselectivity of up to 85/15 in the presence of γ-cyclodextrin by differentiating the two chemically very similar double bonds of 1.

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Regioselective [2 + 2]-photocycloaddition reactions of chiral tetronates - Influence of temperature, pressure, and reaction medium

Abstract

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