Regulation in long-range magnetic ordering in 2-D honeycomb network of (NBu4)[MIIFeIII(ox)3] (MII = mn, fe, co, ni, and cu) family

Hisashi Okawa; Akio Mishima; Haruka Yoshino; Masaaki Ohba

doi:10.1246/cl.171162

Regulation in long-range magnetic ordering in 2-D honeycomb network of (NBu₄)[M^IIFe^III(ox)₃] (M^II = mn, fe, co, ni, and cu) family

Hisashi Okawa, Akio Mishima, Haruka Yoshino, Masaaki Ohba

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Comprehensive studies on 2-D honeycomb-type magnets (NBu₄)[M^IIFe^III(ox)₃] (M^II = Mn, Fe, Co, Ni, and Cu) reveal that the family orders ferrimagnetically at comparable temperatures (2143 K). Moreover, the mixed-valence Fe^IIFe^III compound magnetically orders at an elevated temperature (43 K) relative to other M^IIFe^III compounds (2128 K). The relevance of these magnetic characteristics to other families is reviewed.

Original language	English
Pages (from-to)	444-446
Number of pages	3
Journal	Chemistry Letters
Volume	47
Issue number	4
DOIs	https://doi.org/10.1246/cl.171162
Publication status	Published - 2018
Externally published	Yes

Keywords

2-D honeycomb magnet
Magnetic ordering
Oxalate bridge

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1246/cl.171162

Cite this

@article{0d716897568f470dbd567271f550857a,

title = "Regulation in long-range magnetic ordering in 2-D honeycomb network of (NBu4)[MIIFeIII(ox)3] (MII = mn, fe, co, ni, and cu) family",

abstract = "Comprehensive studies on 2-D honeycomb-type magnets (NBu4)[MIIFeIII(ox)3] (MII = Mn, Fe, Co, Ni, and Cu) reveal that the family orders ferrimagnetically at comparable temperatures (2143 K). Moreover, the mixed-valence FeIIFeIII compound magnetically orders at an elevated temperature (43 K) relative to other MIIFeIII compounds (2128 K). The relevance of these magnetic characteristics to other families is reviewed.",

keywords = "2-D honeycomb magnet, Magnetic ordering, Oxalate bridge",

author = "Hisashi Okawa and Akio Mishima and Haruka Yoshino and Masaaki Ohba",

note = "Funding Information: This work was supported by JSPS KAKENHI Grant Number 16H06519 (Coordination Asymmetry) and 15H03787. Publisher Copyright: {\textcopyright} 2018 The Chemical Society of Japan.",

year = "2018",

doi = "10.1246/cl.171162",

language = "English",

volume = "47",

pages = "444--446",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "4",

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TY - JOUR

T1 - Regulation in long-range magnetic ordering in 2-D honeycomb network of (NBu4)[MIIFeIII(ox)3] (MII = mn, fe, co, ni, and cu) family

AU - Okawa, Hisashi

AU - Mishima, Akio

AU - Yoshino, Haruka

AU - Ohba, Masaaki

PY - 2018

Y1 - 2018

N2 - Comprehensive studies on 2-D honeycomb-type magnets (NBu4)[MIIFeIII(ox)3] (MII = Mn, Fe, Co, Ni, and Cu) reveal that the family orders ferrimagnetically at comparable temperatures (2143 K). Moreover, the mixed-valence FeIIFeIII compound magnetically orders at an elevated temperature (43 K) relative to other MIIFeIII compounds (2128 K). The relevance of these magnetic characteristics to other families is reviewed.

AB - Comprehensive studies on 2-D honeycomb-type magnets (NBu4)[MIIFeIII(ox)3] (MII = Mn, Fe, Co, Ni, and Cu) reveal that the family orders ferrimagnetically at comparable temperatures (2143 K). Moreover, the mixed-valence FeIIFeIII compound magnetically orders at an elevated temperature (43 K) relative to other MIIFeIII compounds (2128 K). The relevance of these magnetic characteristics to other families is reviewed.

KW - 2-D honeycomb magnet

KW - Magnetic ordering

KW - Oxalate bridge

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