Relay catalysis by a ruthenium complex-chiral bronsted acid binary sytem for ternary reaction sequence involving enantioselective pictet-spengler-type cyclization as the key step

Yasunori Toda; Masahiro Terada

doi:10.1055/s-0032-1318302

Relay catalysis by a ruthenium complex-chiral bronsted acid binary sytem for ternary reaction sequence involving enantioselective pictet-spengler-type cyclization as the key step

Yasunori Toda, Masahiro Terada

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

Relay catalysis for a ternary reaction sequence composed of double-bond isomerization, protonation of the double bond, and enantioselective Pictet-Spengler-type cyclization was accomplished using a binary catalytic system consisting of a ruthenium hydride complex and a chiral phosphoric acid as the chiral Bronsted acid catalyst.

Original language	English
Article number	ST-2013-U0012-L
Pages (from-to)	752-756
Number of pages	5
Journal	Synlett
Volume	24
Issue number	6
DOIs	https://doi.org/10.1055/s-0032-1318302
Publication status	Published - 2013

Keywords

asymmetric catalysis
cyclization
isomerization
phenols
protonation

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1055/s-0032-1318302

Cite this

@article{1fb19e103e384ad1b62b1952f651a772,

title = "Relay catalysis by a ruthenium complex-chiral bronsted acid binary sytem for ternary reaction sequence involving enantioselective pictet-spengler-type cyclization as the key step",

abstract = "Relay catalysis for a ternary reaction sequence composed of double-bond isomerization, protonation of the double bond, and enantioselective Pictet-Spengler-type cyclization was accomplished using a binary catalytic system consisting of a ruthenium hydride complex and a chiral phosphoric acid as the chiral Bronsted acid catalyst.",

keywords = "asymmetric catalysis, cyclization, isomerization, phenols, protonation",

author = "Yasunori Toda and Masahiro Terada",

year = "2013",

doi = "10.1055/s-0032-1318302",

language = "English",

volume = "24",

pages = "752--756",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "6",

}

TY - JOUR

T1 - Relay catalysis by a ruthenium complex-chiral bronsted acid binary sytem for ternary reaction sequence involving enantioselective pictet-spengler-type cyclization as the key step

AU - Toda, Yasunori

AU - Terada, Masahiro

PY - 2013

Y1 - 2013

N2 - Relay catalysis for a ternary reaction sequence composed of double-bond isomerization, protonation of the double bond, and enantioselective Pictet-Spengler-type cyclization was accomplished using a binary catalytic system consisting of a ruthenium hydride complex and a chiral phosphoric acid as the chiral Bronsted acid catalyst.

AB - Relay catalysis for a ternary reaction sequence composed of double-bond isomerization, protonation of the double bond, and enantioselective Pictet-Spengler-type cyclization was accomplished using a binary catalytic system consisting of a ruthenium hydride complex and a chiral phosphoric acid as the chiral Bronsted acid catalyst.

KW - asymmetric catalysis

KW - cyclization

KW - isomerization

KW - phenols

KW - protonation

UR - http://www.scopus.com/inward/record.url?scp=84874350476&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84874350476&partnerID=8YFLogxK

U2 - 10.1055/s-0032-1318302

DO - 10.1055/s-0032-1318302

M3 - Article

AN - SCOPUS:84874350476

SN - 0936-5214

VL - 24

SP - 752

EP - 756

JO - Synlett

JF - Synlett

IS - 6

M1 - ST-2013-U0012-L

ER -

Relay catalysis by a ruthenium complex-chiral bronsted acid binary sytem for ternary reaction sequence involving enantioselective pictet-spengler-type cyclization as the key step

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this