Remarkable positive nonlinear effect in the enantioselective glyoxylate-ene reaction catalysed by a chiral titanium complex

Masahiro Terada; Koichi Mikami; Takeshi Nakai

doi:10.1039/C39900001623

Remarkable positive nonlinear effect in the enantioselective glyoxylate-ene reaction catalysed by a chiral titanium complex

Masahiro Terada, Koichi Mikami, Takeshi Nakai

Research output: Contribution to journal › Article › peer-review

101 Citations (Scopus)

Abstract

The enantioselective glyoxylate-ene reaction catalysed by chiral titanium complex derived from partially resolved BINOL is found to exhibit a remarkable level of asymmetric amplification, wherein the optical yield of the product significantly exceeds the enantiomeric purity of the chiral auxiliary employed.

Original language	English
Pages (from-to)	1623-1624
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/C39900001623
Publication status	Published - 1990 Dec 1
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

Access to Document

10.1039/C39900001623

Cite this

@article{b5a548165e3048959a9102ef19205af6,

title = "Remarkable positive nonlinear effect in the enantioselective glyoxylate-ene reaction catalysed by a chiral titanium complex",

abstract = "The enantioselective glyoxylate-ene reaction catalysed by chiral titanium complex derived from partially resolved BINOL is found to exhibit a remarkable level of asymmetric amplification, wherein the optical yield of the product significantly exceeds the enantiomeric purity of the chiral auxiliary employed.",

author = "Masahiro Terada and Koichi Mikami and Takeshi Nakai",

year = "1990",

month = dec,

day = "1",

doi = "10.1039/C39900001623",

language = "English",

pages = "1623--1624",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "22",

}

TY - JOUR

T1 - Remarkable positive nonlinear effect in the enantioselective glyoxylate-ene reaction catalysed by a chiral titanium complex

AU - Terada, Masahiro

AU - Mikami, Koichi

AU - Nakai, Takeshi

PY - 1990/12/1

Y1 - 1990/12/1

N2 - The enantioselective glyoxylate-ene reaction catalysed by chiral titanium complex derived from partially resolved BINOL is found to exhibit a remarkable level of asymmetric amplification, wherein the optical yield of the product significantly exceeds the enantiomeric purity of the chiral auxiliary employed.

AB - The enantioselective glyoxylate-ene reaction catalysed by chiral titanium complex derived from partially resolved BINOL is found to exhibit a remarkable level of asymmetric amplification, wherein the optical yield of the product significantly exceeds the enantiomeric purity of the chiral auxiliary employed.

UR - http://www.scopus.com/inward/record.url?scp=37049077852&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=37049077852&partnerID=8YFLogxK

U2 - 10.1039/C39900001623

DO - 10.1039/C39900001623

M3 - Article

AN - SCOPUS:37049077852

SN - 1359-7345

SP - 1623

EP - 1624

JO - Chemical Communications

JF - Chemical Communications

IS - 22

ER -

Remarkable positive nonlinear effect in the enantioselective glyoxylate-ene reaction catalysed by a chiral titanium complex

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this