Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds

Atsushi Tahara; Yusuke Sunada; Takashi Takeshita; Ryoko Inoue; Hideo Nagashima

doi:10.1039/c8cc04780d

Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds

Atsushi Tahara, Yusuke Sunada, Takashi Takeshita, Ryoko Inoue, Hideo Nagashima

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A disilaruthenacyclic complex (1) showed extremely high catalytic activity for hydrosilane reduction of aldehydes and ketones to silyl ethers and secondary and tertiary amides to the corresponding amines. An σ-CAM mechanism was proposed to explain the activity.

Original language	English
Pages (from-to)	11192-11195
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	79
DOIs	https://doi.org/10.1039/c8cc04780d
Publication status	Published - 2018
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c8cc04780d

Cite this

@article{2eb9f0d958674968908fe0755148c331,

title = "Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds",

abstract = "A disilaruthenacyclic complex (1) showed extremely high catalytic activity for hydrosilane reduction of aldehydes and ketones to silyl ethers and secondary and tertiary amides to the corresponding amines. An σ-CAM mechanism was proposed to explain the activity.",

author = "Atsushi Tahara and Yusuke Sunada and Takashi Takeshita and Ryoko Inoue and Hideo Nagashima",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c8cc04780d",

language = "English",

volume = "54",

pages = "11192--11195",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "79",

}

TY - JOUR

T1 - Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds

AU - Tahara, Atsushi

AU - Sunada, Yusuke

AU - Takeshita, Takashi

AU - Inoue, Ryoko

AU - Nagashima, Hideo

PY - 2018

Y1 - 2018

N2 - A disilaruthenacyclic complex (1) showed extremely high catalytic activity for hydrosilane reduction of aldehydes and ketones to silyl ethers and secondary and tertiary amides to the corresponding amines. An σ-CAM mechanism was proposed to explain the activity.

AB - A disilaruthenacyclic complex (1) showed extremely high catalytic activity for hydrosilane reduction of aldehydes and ketones to silyl ethers and secondary and tertiary amides to the corresponding amines. An σ-CAM mechanism was proposed to explain the activity.

UR - http://www.scopus.com/inward/record.url?scp=85054072328&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85054072328&partnerID=8YFLogxK

U2 - 10.1039/c8cc04780d

DO - 10.1039/c8cc04780d

M3 - Article

C2 - 30229241

AN - SCOPUS:85054072328

SN - 1359-7345

VL - 54

SP - 11192

EP - 11195

JO - Chemical Communications

JF - Chemical Communications

IS - 79

ER -

Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this