Reversible Thermal and Photochemical Interconversion between Cis and Trans Isomers of the Silylene-Bridged Diiron Complex Cp′2Fe2(CO)3(μ-SiHTol) (Cp′ = η-C5Me5, Tol = p-CH3C6H4)

Yasuro Kawano; Hiromi Tobita; Hiroshi Ogino

doi:10.1021/om00038a002

Reversible Thermal and Photochemical Interconversion between Cis and Trans Isomers of the Silylene-Bridged Diiron Complex Cp′₂Fe₂(CO)₃(μ-SiHTol) (Cp′ = η-C₅Me₅, Tol = p-CH₃C₆H₄)

Yasuro Kawano, Hiromi Tobita, Hiroshi Ogino

IEHE - Institute for Excellence in Higher Education (organization affiliation only)

Tohoku University

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Isomerization between cis-Cp′₂Fe₂(CO)₃(μ- SiHTol) (cis-1; Cp′= η-C₅Me₅, Tol = p-CH₃C₆H₄) and trans-1 was found to occur both thermally and photochemically. The composition in the thermal equilibrium state (cis-1:trans-1 = 2:98 in cyclohexane-d₁₂) is considerably different from that in the photostationary state (cis-1: trans-1 = 70:30).

Original language	English
Pages (from-to)	499-500
Number of pages	2
Journal	Organometallics
Volume	11
Issue number	2
DOIs	https://doi.org/10.1021/om00038a002
Publication status	Published - 1992 Feb 1

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title = "Reversible Thermal and Photochemical Interconversion between Cis and Trans Isomers of the Silylene-Bridged Diiron Complex Cp′2Fe2(CO)3(μ-SiHTol) (Cp′ = η-C5Me5, Tol = p-CH3C6H4)",

abstract = "Isomerization between cis-Cp′2Fe2(CO)3(μ- SiHTol) (cis-1; Cp′= η-C5Me5, Tol = p-CH3C6H4) and trans-1 was found to occur both thermally and photochemically. The composition in the thermal equilibrium state (cis-1:trans-1 = 2:98 in cyclohexane-d12) is considerably different from that in the photostationary state (cis-1: trans-1 = 70:30).",

author = "Yasuro Kawano and Hiromi Tobita and Hiroshi Ogino",

year = "1992",

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T1 - Reversible Thermal and Photochemical Interconversion between Cis and Trans Isomers of the Silylene-Bridged Diiron Complex Cp′2Fe2(CO)3(μ-SiHTol) (Cp′ = η-C5Me5, Tol = p-CH3C6H4)

AU - Kawano, Yasuro

AU - Tobita, Hiromi

AU - Ogino, Hiroshi

PY - 1992/2/1

Y1 - 1992/2/1

N2 - Isomerization between cis-Cp′2Fe2(CO)3(μ- SiHTol) (cis-1; Cp′= η-C5Me5, Tol = p-CH3C6H4) and trans-1 was found to occur both thermally and photochemically. The composition in the thermal equilibrium state (cis-1:trans-1 = 2:98 in cyclohexane-d12) is considerably different from that in the photostationary state (cis-1: trans-1 = 70:30).

AB - Isomerization between cis-Cp′2Fe2(CO)3(μ- SiHTol) (cis-1; Cp′= η-C5Me5, Tol = p-CH3C6H4) and trans-1 was found to occur both thermally and photochemically. The composition in the thermal equilibrium state (cis-1:trans-1 = 2:98 in cyclohexane-d12) is considerably different from that in the photostationary state (cis-1: trans-1 = 70:30).

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Reversible Thermal and Photochemical Interconversion between Cis and Trans Isomers of the Silylene-Bridged Diiron Complex Cp′₂Fe₂(CO)₃(μ-SiHTol) (Cp′ = η-C₅Me₅, Tol = p-CH₃C₆H₄)

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