Secure route to the epoxybicyclo[7.3.0]dodecadienediyne core of the kedarcidin chromophore

Kouki Ogawa; Yasuhito Koyama; Isao Ohashi; Itaru Sato; Masahiro Hirama

doi:10.1039/b814595d

Secure route to the epoxybicyclo[7.3.0]dodecadienediyne core of the kedarcidin chromophore

Kouki Ogawa, Yasuhito Koyama, Isao Ohashi, Itaru Sato, Masahiro Hirama

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Formation of an epoxide before 9-membered ring cyclization and SmI ₂ mediated reductive olefination in the presence of the epoxide successfully produced the epoxybicyclo[7.3.0]dodecadienediyne core of the kedarcidin chromophore.

Original language	English
Pages (from-to)	6327-6329
Number of pages	3
Journal	Chemical Communications
Issue number	47
DOIs	https://doi.org/10.1039/b814595d
Publication status	Published - 2008 Dec 11

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b814595d

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title = "Secure route to the epoxybicyclo[7.3.0]dodecadienediyne core of the kedarcidin chromophore",

abstract = "Formation of an epoxide before 9-membered ring cyclization and SmI 2 mediated reductive olefination in the presence of the epoxide successfully produced the epoxybicyclo[7.3.0]dodecadienediyne core of the kedarcidin chromophore.",

author = "Kouki Ogawa and Yasuhito Koyama and Isao Ohashi and Itaru Sato and Masahiro Hirama",

year = "2008",

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AU - Ogawa, Kouki

AU - Koyama, Yasuhito

AU - Ohashi, Isao

AU - Sato, Itaru

AU - Hirama, Masahiro

PY - 2008/12/11

Y1 - 2008/12/11

N2 - Formation of an epoxide before 9-membered ring cyclization and SmI 2 mediated reductive olefination in the presence of the epoxide successfully produced the epoxybicyclo[7.3.0]dodecadienediyne core of the kedarcidin chromophore.

AB - Formation of an epoxide before 9-membered ring cyclization and SmI 2 mediated reductive olefination in the presence of the epoxide successfully produced the epoxybicyclo[7.3.0]dodecadienediyne core of the kedarcidin chromophore.

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JO - Chemical Communications

JF - Chemical Communications

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Secure route to the epoxybicyclo[7.3.0]dodecadienediyne core of the kedarcidin chromophore

Abstract

ASJC Scopus subject areas

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