Selective crystallization of dysprosium complex from neodymium/dysprosium mixture enabled by cooperation of coordination and crystallization

Atsuko Masuya-Suzuki; Koji Hosobori; Ryota Sawamura; Yumika Abe; Ryunosuke Karashimada; Nobuhiko Iki

doi:10.1039/d1cc06174g

Selective crystallization of dysprosium complex from neodymium/dysprosium mixture enabled by cooperation of coordination and crystallization

Atsuko Masuya-Suzuki, Koji Hosobori, Ryota Sawamura, Yumika Abe, Ryunosuke Karashimada, Nobuhiko Iki

ENV - Frontier Science for Advanced Environment

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Designing a molecular-level Ln3+ separation system remains a challenge for developing next-generation separation methodologies. Herein, we report crystallization-based Nd3+/Dy3+ separation using a tripodal Schiff base ligand. Highly selective crystallization of the Dy3+ complex was enabled by cooperation between the coordination and crystallization processes.

Original language	English
Pages (from-to)	2283-2286
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	14
DOIs	https://doi.org/10.1039/d1cc06174g
Publication status	Published - 2022 Feb 18

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d1cc06174g

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abstract = "Designing a molecular-level Ln3+ separation system remains a challenge for developing next-generation separation methodologies. Herein, we report crystallization-based Nd3+/Dy3+ separation using a tripodal Schiff base ligand. Highly selective crystallization of the Dy3+ complex was enabled by cooperation between the coordination and crystallization processes. ",

author = "Atsuko Masuya-Suzuki and Koji Hosobori and Ryota Sawamura and Yumika Abe and Ryunosuke Karashimada and Nobuhiko Iki",

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AU - Masuya-Suzuki, Atsuko

AU - Hosobori, Koji

AU - Sawamura, Ryota

AU - Abe, Yumika

AU - Karashimada, Ryunosuke

AU - Iki, Nobuhiko

PY - 2022/2/18

Y1 - 2022/2/18

N2 - Designing a molecular-level Ln3+ separation system remains a challenge for developing next-generation separation methodologies. Herein, we report crystallization-based Nd3+/Dy3+ separation using a tripodal Schiff base ligand. Highly selective crystallization of the Dy3+ complex was enabled by cooperation between the coordination and crystallization processes.

AB - Designing a molecular-level Ln3+ separation system remains a challenge for developing next-generation separation methodologies. Herein, we report crystallization-based Nd3+/Dy3+ separation using a tripodal Schiff base ligand. Highly selective crystallization of the Dy3+ complex was enabled by cooperation between the coordination and crystallization processes.

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Selective crystallization of dysprosium complex from neodymium/dysprosium mixture enabled by cooperation of coordination and crystallization

Abstract

ASJC Scopus subject areas

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