Selective formation of 1-propanol via ethylene hydroformylation over the catalyst originated from RhVO4

Takashi Yamagishi; Shin ichi Ito; Keiichi Tomishige; Kimio Kunimori

doi:10.1016/j.catcom.2005.03.008

Selective formation of 1-propanol via ethylene hydroformylation over the catalyst originated from RhVO₄

Takashi Yamagishi, Shin ichi Ito, Keiichi Tomishige, Kimio Kunimori

ENG - Applied Chemistry

University of Tsukuba

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

It is found that vanadia-modified Rh/SiO₂ catalyst (V-Rh/SiO₂) exhibited high selectivity of 1-propanol formation in ethylene hydroformylation. The performance of V-Rh/SiO₂ was much dependent on the calcination temperature and the formation of RhVO₄ mixed oxide crystallites. The active sites for 1-propanol formation can be formed by the reduction of the RhVO₄ mixed oxide.

Original language	English
Pages (from-to)	421-425
Number of pages	5
Journal	Catalysis Communications
Volume	6
Issue number	6
DOIs	https://doi.org/10.1016/j.catcom.2005.03.008
Publication status	Published - 2005 Jun

Keywords

1-propanol
Additive effect
Ethene
Hydroformylation
Rh-VO interaction
RhVO

Access to Document

10.1016/j.catcom.2005.03.008

Cite this

@article{56f545ae6e01421aaca993b23a072788,

title = "Selective formation of 1-propanol via ethylene hydroformylation over the catalyst originated from RhVO4",

abstract = "It is found that vanadia-modified Rh/SiO2 catalyst (V-Rh/SiO2) exhibited high selectivity of 1-propanol formation in ethylene hydroformylation. The performance of V-Rh/SiO2 was much dependent on the calcination temperature and the formation of RhVO4 mixed oxide crystallites. The active sites for 1-propanol formation can be formed by the reduction of the RhVO4 mixed oxide.",

keywords = "1-propanol, Additive effect, Ethene, Hydroformylation, Rh-VO interaction, RhVO",

author = "Takashi Yamagishi and Ito, {Shin ichi} and Keiichi Tomishige and Kimio Kunimori",

year = "2005",

month = jun,

doi = "10.1016/j.catcom.2005.03.008",

language = "English",

volume = "6",

pages = "421--425",

journal = "Catalysis Communications",

issn = "1566-7367",

publisher = "Elsevier",

number = "6",

}

TY - JOUR

T1 - Selective formation of 1-propanol via ethylene hydroformylation over the catalyst originated from RhVO4

AU - Yamagishi, Takashi

AU - Ito, Shin ichi

AU - Tomishige, Keiichi

AU - Kunimori, Kimio

PY - 2005/6

Y1 - 2005/6

N2 - It is found that vanadia-modified Rh/SiO2 catalyst (V-Rh/SiO2) exhibited high selectivity of 1-propanol formation in ethylene hydroformylation. The performance of V-Rh/SiO2 was much dependent on the calcination temperature and the formation of RhVO4 mixed oxide crystallites. The active sites for 1-propanol formation can be formed by the reduction of the RhVO4 mixed oxide.

AB - It is found that vanadia-modified Rh/SiO2 catalyst (V-Rh/SiO2) exhibited high selectivity of 1-propanol formation in ethylene hydroformylation. The performance of V-Rh/SiO2 was much dependent on the calcination temperature and the formation of RhVO4 mixed oxide crystallites. The active sites for 1-propanol formation can be formed by the reduction of the RhVO4 mixed oxide.

KW - 1-propanol

KW - Additive effect

KW - Ethene

KW - Hydroformylation

KW - Rh-VO interaction

KW - RhVO

UR - http://www.scopus.com/inward/record.url?scp=19844383860&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=19844383860&partnerID=8YFLogxK

U2 - 10.1016/j.catcom.2005.03.008

DO - 10.1016/j.catcom.2005.03.008

M3 - Article

AN - SCOPUS:19844383860

SN - 1566-7367

VL - 6

SP - 421

EP - 425

JO - Catalysis Communications

JF - Catalysis Communications

IS - 6

ER -

Selective formation of 1-propanol via ethylene hydroformylation over the catalyst originated from RhVO₄

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this