Selective hydrogenation of higher saturated carboxylic acids to alcohols using a ReOx-Pd/SiO2 catalyst

Yasuyuki Takeda; Yoshinao Nakagawa; Keiichi Tomishige

doi:10.1039/c2cy20302b

Selective hydrogenation of higher saturated carboxylic acids to alcohols using a ReO_x-Pd/SiO₂ catalyst

Yasuyuki Takeda, Yoshinao Nakagawa, Keiichi Tomishige

ENG - Applied Chemistry

Research output: Contribution to journal › Article › peer-review

91 Citations (Scopus)

Abstract

Higher fatty alcohols were synthesized in high yield (>92%) by direct hydrogenation of fatty acids catalyzed by ReO_x-Pd/SiO₂. High catalytic performance of ReO_x-Pd/SiO₂ can be generated by the synergy between ReO_x and Pd. Preferential adsorption of the carboxylic acid to alcohols prohibited the overreaction of alcohols to alkanes.

Original language	English
Pages (from-to)	2221-2223
Number of pages	3
Journal	Catalysis Science and Technology
Volume	2
Issue number	11
DOIs	https://doi.org/10.1039/c2cy20302b
Publication status	Published - 2012 Nov

ASJC Scopus subject areas

Catalysis

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abstract = "Higher fatty alcohols were synthesized in high yield (>92%) by direct hydrogenation of fatty acids catalyzed by ReOx-Pd/SiO2. High catalytic performance of ReOx-Pd/SiO2 can be generated by the synergy between ReOx and Pd. Preferential adsorption of the carboxylic acid to alcohols prohibited the overreaction of alcohols to alkanes.",

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AB - Higher fatty alcohols were synthesized in high yield (>92%) by direct hydrogenation of fatty acids catalyzed by ReOx-Pd/SiO2. High catalytic performance of ReOx-Pd/SiO2 can be generated by the synergy between ReOx and Pd. Preferential adsorption of the carboxylic acid to alcohols prohibited the overreaction of alcohols to alkanes.

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Selective hydrogenation of higher saturated carboxylic acids to alcohols using a ReO_x-Pd/SiO₂ catalyst

Abstract

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